Photoelectrochemical Cell

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Transcript Photoelectrochemical Cell

Global Energy Perspective
• Present Primary Power Mix
• Future Constraints Imposed by Sustainability
• Theoretical and Practical Energy Potential of Various Renewables
• Challenges to Exploit Renewables Economically
on the Needed Scale
Nathan S. Lewis, California Institute of Technology
Division of Chemistry and Chemical Engineering
Pasadena, CA 91125
http://nsl.caltech.edu
Mean Global Energy Consumption, 1998
5
4.5
4
3.5
3
TW 2.5
2
1.5
1
0.5
0
4.52
2.7
2.96
1.21
0.828
0.286
Oil
Gas
Coal
Total: 12.8 TW
0.286
Hydro Biomass Renew Nuclear
U.S.: 3.3 TW (99 Quads)
US Energy Flow -1999
Net Primary Resource Consumption 102 Exajoules
Energy From Renewables,
1998
Renewables
1
3E-1
1E-1
0.1
1E-2
TW
0.01
2E-3
1.6E-3
0.001
1E-4
5E-5
0.0001
10
7E-5
-5
Elect
Elec
Heat
Heat
EtOH
EtOH
Biomass
Wind Solar
PVSolar
Low
T Sol
Geoth Marine
Marine
Wind
Sol PV
SolThTh.
LowT
Sol HtHydro
Hydro Geoth
Today: Production Cost of Electricity
(in the U.S. in 2002)
25-50 ¢
25
20
15
Cost
10
1-4 ¢
2.3-5.0 ¢ 6-8 ¢
5-7 ¢
6-7 ¢
5
0
Coal
Gas
Oil
Wind
Nuclear
Solar
Energy Costs
$0.05/kW-hr
14
12
8
6
Brazil
$/GJ
4
Europe
10
2
0
Coal
Oil
Biomass
Elect
www.undp.org/seed/eap/activities/wea
Energy Reserves and Resources
180000
160000
140000
120000
100000
(Exa)J
80000
60000
40000
20000
0
Rsv=Reserves
Res=Resources
Unconv
Conv
Oil
Rsv
Oil
Res
Reserves/(1998 Consumption/yr)
Oil
Gas
Coal
40-78
68-176
224
Gas
Rsv
Gas
Res
Coal
Rsv
Coal
Res
Resource Base/(1998 Consumption/yr)
51-151
207-590
2160
Conclusions
•
Abundant, Inexpensive Resource Base of Fossil Fuels
• Renewables will not play a large role in primary power generation
unless/until:

technological/cost breakthroughs are achieved, or

unpriced externalities are introduced (e.g., environmentally
-driven carbon taxes)
Energy and Sustainability
•
“It’s hard to make predictions, especially about the future”
•
M. I. Hoffert et. al., Nature, 1998, 395, 881, “Energy Implications
of Future Atmospheric Stabilization of CO2 Content
adapted from IPCC 92 Report: Leggett, J. et. al. in
Climate Change, The Supplementary Report to the
Scientific IPCC Assessment, 69-95, Cambridge Univ.
Press, 1992
Population Growth to
10 - 11 Billion People
in 2050
Per Capita GDP Growth
at 1.6% yr-1
Energy consumption per
Unit of GDP declines
at 1.0% yr -1
Total Primary Power vs Year
1990: 12 TW 2050: 28 TW
Carbon Intensity of Energy Mix
M. I. Hoffert et. al., Nature, 1998, 395, 881
CO2
Emissions
Data from Vostok
Ice Core
Projected Carbon-Free Primary Power
Hoffert et al.’s Conclusions
• “These results underscore the pitfalls of “wait and see”.”
• Without policy incentives to overcome socioeconomic inertia,
development of needed technologies will likely not occur soon
enough to allow capitalization on a 10-30 TW scale by 2050
• “Researching, developing, and commercializing carbon-free
primary power technologies capable of 10-30 TW by the mid-21st
century could require efforts, perhaps international, pursued with
the urgency of the Manhattan Project or the Apollo Space
Program.”
Lewis’ Conclusions
• If we need such large amounts of carbon-free power, then:
• current pricing is not the driver for year 2050 primary
energy supply
• Hence,
• Examine energy potential of various forms of renewable
energy
• Examine technologies and costs of various renewables
• Examine impact on secondary power infrastructure and
energy utilization