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New England
Roofing Industry
Partnership
Health Hazards & Hazard
Communication
1926.59
SUBPART
D Health Hazards & Hazard Communication
Training Objectives
After
completing this unit, you will be
able to:
– Explain the purpose and content of the OSHA
Hazard Communication Standard.
– Identify basic types of health hazards from
chemicals used on the work site.
– Identify routes of entry & potential health effects.
– Explain the purpose & identify the components of a
Material Safety Data Sheet (MSDS).
– Find hazard control information on an MSDS.
– Identify manufacturer’s and standardized labeling
systems.
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SUBPART
D Health Hazards & Hazard Communication
References
29
CFR 1926.59, Subpart D, Hazard
Communication
29 CFR 1910.1200 Subpart Z, Hazard
Communication
National Fire Protection Association
(NFPA)
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SUBPART
D Health Hazards & Hazard Communication
The Dangers of Chemicals
Are
chemicals really worth worrying
about?
– A recent study shows that exposure to
harmful substances causes 18% of all on
the job deaths in construction!
– This does not include those workers who
get long term diseases from exposures.
– Asbestos, fiberglass, adhesives, and paint
products cause thousands of cases of lung
disease among construction workers.
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SUBPART
D Health Hazards & Hazard Communication
How Chemicals Get Inside Us
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Hazards of Chemicals…
There are 2 basic types of chemical hazards
– Physical Hazards
– Health Hazards
The first rule of Chemical safety is… "Know what
you are working with and how to protect yourself
and others“
Physical Hazards…
Chemicals are classified as having Physical Hazards if they
are
Explosive
Compressed Gas
Combustible Liquids
Flammable
Unstable
Water Reactive
Oxidizers
Physical Hazards…
Some chemicals may be safe by themselves,
but become dangerous when in contact with
other substances.
Chemicals with Physical
Hazards…
Used only by trained employees
Stored in a safe manner
Never mixed with other chemicals unless by
an approved procedure
Health Hazards
Chemicals are classified as being a health
hazard if they:
Can cause cancer
Are poisonous (toxic)
Cause harm to your skin, internal organs,
or nervous system
Are corrosive - such as acids
Cause allergic reactions after repeated
exposure
SUBPART
D Health Hazards & Hazard Communication
Routes of Entry
Inhalation
– Usually our biggest concern due to very
large surface area of the lungs.
Ingestion
– A concern where hand-to-mouth actions
occur, for example eating or smoking.
Skin Absorption
– Can lead to a double exposure with
inhalation of some solvents.
Injection
– Into the skin, such as compressed air or
high pressure paint spray.
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SUBPART
D Health Hazards & Hazard Communication
Inhalation Hazards
Each
year respiratory hazards cause
illness and death for thousands of
construction workers.
The hazards in the air can be either:
– Gases, Vapors, such as ADHESIVE
VAPORS
– Particulates
• Dust, fibers, fumes, such as SILICA DUST
– Oxygen-Deficient Atmospheres
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SUBPART
D Health Hazards & Hazard Communication
Gases and Vapors
Gases-
– formless at room temperature; things like
carbon monoxide, methane and propane.
Vapors-
– formed when liquids evaporate; things
like paint vapors, adhesive vapors, and
gasoline vapors.
Either can get into your bloodstream by
breathing them into your lungs. Once in
your blood they can damage your organs.
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SUBPART
D Health Hazards & Hazard Communication
Oxygen-Deficient Atmospheres
Most
often found in confined spaces.
Considered immediately dangerous to
life and health (IDLH).
IDLH situations will cause death or
serious injury within 30 minutes.
19.5% oxygen is the lowest legal limit.
Lack of oxygen can damage your brain.
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D Health Hazards & Hazard Communication
Particulates
Dusts
– produced by grinding, sanding, cutting, and
mixing.
Mists
– given off when a liquid is sprayed.
Fumes– tiny particles given off when metals or other solid
materials are vaporized, then cooled.
– For example – welding fumes.
Health effect will depend on origin and particle
size. Finer material can penetrate deep into
your lungs.
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SUBPART
D Health Hazards & Hazard Communication
How Chemicals Affect Us
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SUBPART
D
Health Hazards & Hazard Communication
Once A Chemical Gets In
Depending
on its toxicity and how
much, you were exposed to, it may:
– Irritate or injure your nose, mouth, throat,
or lungs.
– Get into your blood stream through your
lungs or skin.
– Have an additive, or synergistic, effect
with some other compound.
– Stay in your body for a long time.
– Damage certain organs, or systems.
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SUBPART
D Health Hazards & Hazard Communication
Working Safely With Chemicals
We
can prevent chemical exposure
and related illness by:
– Knowing everything we can about the
chemicals we work with.
– Applying the OSHA Hazard
Communication Standard which was
designed to make sure workers know
about the chemicals they work with.
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SUBPART
D Health Hazards & Hazard Communication
Hazard Communication Standard
The
Hazard Communication Standard
requires employers to:
– Get and provide Material Safety Data
Sheets (MSDSs) on each chemical.
– Use only chemicals that are labeled.
– Inform and train workers about the
chemicals.
– Have a written program which includes a
list of all chemicals being used.
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What’s wrong with this picture?
SUBPART
D Health Hazards & Hazard Communication
Container Labeling
All chemicals must be labeled.
Employers may use the manufacturer’s label
which came on the container.
Employers may also use standardized
systems such as the National Fire Protection
Association (NFPA) label.
– Note: As a worker you are permitted to have an
unlabeled container if you have complete control
over the container at all times and you only have
as much as you will use-up for the task. Walking
away from it, even for a moment, is losing control.
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SUBPART
D Health Hazards & Hazard Communication
Check It Out!
One of the most
effective ways to
learn about the
chemicals you use is
to read the label.
What you learn may
surprise you.
More importantly it
will give you the
knowledge to help
protect yourself.
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Employee Information and
Training
Employers must provide employees
information and training on hazardous
chemicals in their work area:
– At the time of their initial assignment
– Whenever a new physical or health
hazard the employees have not
previously been trained about is
introduced into their work area
Training may cover categories of hazards
Employee Information
Employers must inform employees:
– Of the training requirements of
this section (1910.1200 (h)
Employee information and
training.);
– Any operations in their work area
where hazardous chemicals are
present;
– The location and availability of the
written hazard communication
program
Employee Information
Employers must inform employees:
– The location and availability of the list of
hazardous chemicals
– The location and availability of material safety
data sheets
Employee Training
Employee training shall include at least:
– Methods and observations that may be used to detect the
presence or release of a hazardous chemical in the work
area
– The physical and health hazards of chemicals in the work
area
– Measures employees can take to protect themselves
– Details of the employers specific program
New Hazard Information
One important function of the individual(s)
in charge of maintaining MSDS for the
employer is to replace current MSDS with
the revised version, when it is received.
Companies can have copies in several
locations, so updating all copies requires
a conscientious effort by the individual(s)
responsible for maintaining MSDS.
MSDS availability off-site
For employees who work off-site:
– MSDS may be kept at the central location
– In an emergency, the employer must have
provisions in place to ensure that employees can
immediately obtain the required information
SUBPART
D Health Hazards & Hazard Communication
16
Material Safety Data Sheet (MSDS)
SUBPART
D Health Hazards & Hazard Communication
MSDS - Product Information
Chemical
name.
Who makes it.
The manufacturer’s address.
The manufacturer’s phone number.
The date the MSDS was prepared.
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SUBPART
D Health Hazards & Hazard Communication
MSDS - Chemical/Physical
Properties
Physical
and chemical characteristics
help predict a chemical’s behavior.
– Boiling point, vapor pressure, vapor
density, solubility in water, specific
gravity, melting point, evaporation rate,
and appearance/odor.
– For example,
• A chemical with a vapor density greater than 1
will have a vapor heavier than air, like
gasoline.
• A liquid with a specific gravity less than 1 will
float on water, like oil.
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SUBPART
D Health Hazards & Hazard Communication
MSDS - Fire & Explosion Data
We
can use the MSDS to find out about
the fire and explosion hazard of a
product, things like:
– The Chemical’s Flash Point.
– What type of extinguisher to use.
– Any special fire fighting precautions.
– What not to mix it with.
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SUBPART
D Health Hazards & Hazard Communication
FLASH POINT
The
temperature the chemical must
reach to give off enough vapor for
fire or explosion if an ignition source
or spark was there.
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D Health Hazards & Hazard Communication
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MSDS - Health Hazard Information
SUBPART
D Health Hazards & Hazard Communication
Exposure Limits
Limits
are based on laboratory
research and are set based on what
85% of the population can stand
without getting sick.
The
number is based on the average
concentration over an 8-hour day, 40
hours per week for your whole
working life.
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D Health Hazards & Hazard Communication
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Exposure Limits2
Threshold
Limit Values (TLVs) are from
current research.
Permissible Exposure Limits (PELs) are
OSHA law but the levels may be higher as
they depend on older research results.
On your MSDS take note, some chemicals
may have a TLV lower than the PEL.
SUBPART
D Health Hazards & Hazard Communication
PELs and TLVs
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SUBPART
D Health Hazards & Hazard Communication
MSDS - Protective Measures
We
can use the MSDS to find out if
ventilation is required, and things like:
– Specific type of respirator needed.
– What type of gloves to use.
– What type of eye and face protection is
needed.
– Any other protective equipment and
protective measures needed.
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SUBPART
D Health Hazards & Hazard Communication
MSDS - Handling Spills & Leaks
We
can use the MSDS to find out what to
do with leaks and spills, things like:
– Procedures for clean-up.
– Disposal after clean-up.
– Any other special precautions such as
insuring good ventilation during clean-up.
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SUBPART
D Health Hazards & Hazard Communication
MSDS - Special Precautions
We
can use the MSDS to find out if there
are any special precautions for handling
and storage, things like:
– Avoiding ignition sources.
– Avoiding storage above 1000 Fahrenheit.
– What it should not be stored near such as
oxygen tanks.
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SUBPART
D Health Hazards & Hazard Communication
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Most Importantly!
Check
the health hazards section for
routes of entry and symptoms of
overexposure.
Check the protective measures section
for safe handling and PPE selection.
Check the fire and explosion data section
for unusual fire & explosion potential.
Read the MSDS before using a chemical!
Read the label before using a chemical!
SUBPART
D Health Hazards & Hazard Communication
NFPA Label
National
Fire Protection Association
The higher the number in the blue
box (max. is 4), the greater the health
hazard. Check the MSDS.
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SUBPART
D
Health Hazards & Hazard Communication
HMIS Label
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SUBPART
D Health Hazards & Hazard Communication
Access to Information
Material
safety data sheets must be
available whenever you want them.
– Computerized MSDS is OK, if
immediately available on the job.
You
must also be able to see the
company’s written hazard
communication program including
the list of chemicals.
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SUBPART
D Health Hazards & Hazard Communication
Case Study: What went wrong?
A laborer was given the
job of thinning a large
stock pile of oil-based
paints while inside a
small storage building.
At the end of the
second day, he was
found unconscious. He
was taken to the hospital
with an irregular heart
beat & almost died.
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SUBPART
D Health Hazards & Hazard Communication
Subpart D - Occupational Health
(1926.50 - 66)
Gases, vapors, fumes, dusts & mists - Exposure
55(a)
63
Lead - Exposure assessment
Standard - 1926.
62(d)(1)(i)
59
Gases, vapors, fumes, dusts & mists - Controls
55(b)
44
Employee exposure assessment - Biological monitoring
62(d)(2)(v)(E)
37
Hazard Communication - Written Program
59(e)(1)
31
Employee exposure assessment - Appropriate PPE
62(d)(2)(v)(B)
31
34