Transcript atom

Chapter 4 Atomic
Structure
Section 4-1
Objectives
• Describe ancient Greek models of matter
• List the main points of Dalton’s atomic
theory and describe his evidence for the
existence of atoms
• Explain how Thomson and Rutherford used
data from experiments to produce their
atomic models
derivation of the
word “atom” ?
• “a” – not
• “tomos” - cutting
• Matter can only be subdivided
as small as an elemental
particle: THE ATOM
Democritus
• About 400 BC
• World is made of 2 things
– 1) empty space
– 2) tiny particles called “atoms”
Aristotle
• Matter is continuous and NOT MADE
OF ATOMS
• few believers in atoms for nearly
2,000 yrs
• WHY?????????????????
Dalton’s Theory
• Dalton produced the theory that all
matter is made up of individual
particles called atoms, which cannot
be divided.
Main Points to Dalton’s
Theory
• All elements are composed of atoms
• All atoms of the same element have the
same mass, and atoms of different
elements have different masses
• Compounds contain atoms of more than one
element
• In a particular compound, atoms of
different elements always combine in the
same way.
Early Research on
Atomic Particles
• Eventually exceptions were
discovered to Dalton’s Atomic
Theory……..
J.J Thompson
• Created Cathode Ray Tube
Experiment
Cathode Ray Studies of the
mid 1800’s
What did these
observations mean?
• Glowing ray in cathode tube was made of
particles
• Particles that composed cathode rays are
negatively charged called electrons
• Thomson’s experiments provided the first
evidence that atoms are made of even
smaller particles
Thomson’s Model
•
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•
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Called “Plum Pudding”
Looks like chocolate chip ice cream
Chocolate is negative particles
Vanilla ice cream is positively charged
matter
Rutherford’s Atomic
Theory
• The gold foil experiment
Teacher Demo
Investigating Charged Objects
• Pg 102
Observations
• Most positive particles
passed through the gold foil
• About 1 in 8,000 particles
bounced almost straight back
Discovery of the Nucleus
• Rutherford’s experiment discovered the
nucleus
• Nucleus is a dense, positively charged mass
located in the center of the atom.
• According to Rutherford’s model, all of an
atom’s positive charge is concentrated in
its nucleus.
Beaker Breaker
1. The gold foil experiment was done
by _________
2. The cathode ray tube experiment
was done by ___________
3. Who discovered the
nucleus?____________
Section 4-2
The structure of an Atom
Objectives
• Identify three subatomic particles
and compare their properties
• Distinguish the atomic number of an
element from the mass number of an
isotope, and use these numbers to
describe the structure of atoms
Definitions
•
Use your book to define the following
2.
Electron-
3.
Neutron-
4.
Atomic number-
5.
Mass Number-
6.
Isotopes-
1.
Proton –
Properties of Subatomic
Particles
• Protons, electrons, and neutrons are
subatomic particles
Protons
• A proton is a positively charged
subatomic particle that is found in
the nucleus of an atom
• Each proton is assigned a 1+ charge
• Some nuclei contain more than 100
protons
Electrons
• An electron is a negatively charged
subatomic particle that is found in
the space outside the nucleus.
• Each electron has a charge of 1 -.
Neutrons
• A neutron is a neutral subatomic particle
that is found in the nucleus of an atom.
• It has a mass almost exactly equal to that
of a proton
• James Chadwick designed an experiment
to show that neutrons exist.
Comparing Subatomic
Particles
• Protons, electrons, and neutrons can be
distinguished by mass, charge and location in an
atom.
• Protons and neutrons have almost the same mass
• Electrons have a charge that is opposite of the
charge of a proton
• Protons and neutrons are found in the nucleus, but
electrons are found in the space outside the
nucleus.
Atomic Number
• The atomic number of an element equals
the number of protons in an atom of that
element
• Atoms of different elements have
different numbers of protons.
• Atomic number also tells you the number
of electrons
• Ex: Sulfur atomic number = 16
• Ex : Carbon (C ) atomic number = 6
Mass Number
• The mass number of an atom is the sum of the
protons and neutrons in the nucleus of that atom
• Ex: Aluminum has 13 protons and 14 neutrons has
a mass number of 27
• If you know the atomic number and the mass
number of an atom, you can find the number of
neutrons by subtracting.
•
Mass number – Atomic number = Number of neutrons
Isotopes
• Isotopes of an element have the same
atomic number but different mass
numbers because they have different
numbers of neutrons.
• Ex Oxygen -16 ( 8 protons and 8 neutrons)
Oxygen – 17 ( 8 protons and 9 neutrons)
Oxygen -18 ( 8 protons and 10 neutrons)
Beaker Breaker
• A __________is a neutral subatomic
particle that is found in the nucleus
• An electron has a _________charge
• ______and ________are located in
the nucleus, while_______are
located outside the nucleus
Section 4-3 Modern Atomic Theory
Objectives
• Describe Bohr’s model of the atom and the
evidence for energy levels
• Explain how the electron cloud model
represents the behavior and locations of
electron in atoms
• Distinguish the ground state from excited
states of an atom based on electron
configurations
Bohr’s Model
• Model of atom looks like a solar
system with planets revolving around
a sun
• Model focused on electrons
Bohr’s Model and energy
levels
• The possible energies that electrons in an
atom can have are called energy levels.
• Energy levels are like steps on a staircase,
an electron cannot exist between energy
levels
• An electron in an atom can move from one
energy level to another when the atom
gains or loses energy
Evidence for Energy
Levels
• Scientist can measure the energy
gained when electrons absorb energy
and move to a higher energy level.
• They can measure the energy
released when the electron returns
to a lower energy level
Beaker Breaker
1.
An___________ cloud is a visual model
of the most likely locations for electrons
in an atom.
2. Which scientist is the responsible for
the discovery of neutrons?
3. When electrons move to a higher energy
level do they absorb or release energy?
Flame Test Lab
• Read page 116 “evidence for energy
levels” in the book
Question :
How do these substances produces
light of different colors?
Electron Cloud Model
• An electron cloud is a visual model of the
most likely locations for electrons in an
atom.
• Scientists use the electron cloud model to
describe the possible locations of
electrons around the nucleus
• Ex: blades on a propeller of an airplane
Modern Atom
1.
Louis de Broglie – proposes that moving
particles like electrons have some properties of
waves.
2.
Erwin Schrodinger develops mathematical
equations to describe the motion of electrons in
atoms (electron cloud).
3.
James Chadwick- confirms the existence of
neutrons in the nucleus, which have no charge
Drawings of Atoms
Atomic Orbitals
• An orbital is a region of space around the
nucleus where an electron is likely to be
found
• An electron cloud is a good approximation
of how electrons behave in their orbitals.
• Higher energy levels have more than one
orbital
Electron Configurations
• An electron configuration is the
arrangement of electrons in the orbitals
of an atom
• The most stable electron configuration is
the one in which the electrons are in
orbitals with the lowest possible energies
• When all the electrons in an atom have the
lowest possible energies, the atom is said
to be in its ground state.