Nomenclature
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Transcript Nomenclature
Nomenclature
Naming compounds
Writing Formulas
Naming Compounds
Binary Compounds
Compounds that contain two elements
• Name the first element
• Name the second element using an “ide”
ending
• Check the oxidation number of the first
element
• If it has more than one positive value, use a
Roman numeral to indicate the number that
was used
CaCl2
Calcium
Calcium chloride
Ca is +2 only
No Roman numeral needed
Calcium chloride
CCl4
Carbon
Carbon chloride
C is -4, +2 and +4
Since there are two positive choices,
use a Roman numeral
+4
-4
+4
-1
=0
C Cl4
Carbon IV chloride
Naming Compounds
Ternary Compounds
Compounds that contain more than two elements
• Polyatomic ion is present
• Two or more elements that join together and act like one
substance
• Found on Table E
Identify the polyatomic used
Name the first substance
Name the second substance
Check the oxidation number of the first element
• If it has more than one positive value, use a Roman
numeral to indicate the number that was used
K2SO4
Potassium
Potassium sulfate
Potassium is +1 only
No Roman numeral is needed
Potassium sulfate
Cu(NO3) 2
Copper
Copper nitrate
Copper can be +1 or +2
Needs a Roman numeral
+2
-2
+2
-1
=0
Cu (NO3)2
Copper II nitrate
NH4Cl
Ammonium
Ammonium chloride
Ammonium ion is +1
No choice means no Roman numeral
needed
Ammonium chloride
Prefix System
Use a prefix INSTEAD OF a Roman numeral
Mono
2 elements
Tri
only used for the 2nd element
Di
1
3 elements
Tetra
4 elements
CO2
Carbon dioxide
Suffix System
Used INSTEAD OF a Roman numeral
“-ic
Highest oxidation state
“-ous”
Lowest positive oxidation state
NiCl2
Nickel II chloride
Nickelous chloride
B. Writing Formulas
Use ending to tell if compound is binary or
ternary
Binary usually ends in “ide”
•
Ternary usually ends in “ate” or “ite”
Write the symbols
Assign oxidation numbers
[except hydroxide and cyanide]
Positive atom on left, negative on right
Reduce if possible and “criss-cross”
These numbers become the subscripts of
the formula
Strontium phosphide
“ide” means binary
Strontium (Sr)
Phosphide is phosphorus (P)
Sr+2 P-3
Sr3P2
Iron II Oxide
“ide” means binary
Iron (Fe)
Oxide is oxygen (O)
Fe+2 O-2
Fe2O2
reduce
FeO
Manganese IV Carbonate
“ate” means ternary
Manganese (Mn)
Carbonate is a polyatomic ion
(CO3-2)
Mn+4 CO3-2
Mn2(CO3 )4
reduce
Mn (CO3 )2
Ferrous sulfide
ferr
-ous
represents lowest positive state
sulfide
represents Fe (iron)
represents sulfur
Fe+2 S-2
Fe2S2 reduces to
• FeS
Diphosphorus trioxide
NO CHARGES ASSIGNED
NO CRISS-CROSSING
Diphosphorus
P2
Trioxide
O3
Formula
P2O3