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What is an Ultracapacitor?:
Ultracapacitors Are
A 100-year-old technology enhanced by modern materials
Based on polarization of an electrolyte, high surface area
electrodes, and extremely small charge separation
Known as Electrochemical Double Layer Capacitors and
Supercapacitors
What is an Ultracapacitor?:
Ultracapacitors Are
Dielectric
C = er A/d
Minimize (d)
Maximize (A)
Electrolyte
E = 1/2 CV2
Film foil
Electrode
ECDL
Separator
Basic Model
Series/Parallel configurations
Changes capacitor size; profiles are the same
Series configurations
Capacitance decreases, Series Resistance increases
Cs=Ccell/(#of cells in series) Rs=Rcell*(# of cells in series)
Parallel configurations
Capacitance increases, Series Resistance decreases
CP=Ccell*(# of cells in parallel)
RP=Rcell/(# cells in parallel)
Current controlled
Use output current profile to determine dV/dt
dV = I * (dt/C + ESR)
What is an Ultracapacitor?:
Performance Characteristics
Ultracapacitors perform mid-way between conventional
capacitors and electrochemical cells (batteries)
Fast charge and discharge capability
Highly reversible process, hundreds of thousands of cycles
Lower energy than a battery
~10% of battery energy
Greater energy than electrolytic capacitors
Excellent low temperature performance
Application Model
When Can I Use an Ultracapacitor?
Applications that require high reliability back-up power
solutions
Short term bridge power (1 - 60 seconds) for transfer to
secondary source or orderly shut down
Power quality ride-through
momentary severe voltage sags
Power buffer for large momentary in-rush or power
surges
to
compensate
for
Back-Up Power Support
Ultracapacitors provide peak power…
...and back-up power.
Available Power
Required Power
Ultracapacitor Backup Power
Peak Power Shaving
Ultracapacitors provide peak power...
Available
Power
Required Power
Ultracapacitor Peak Power
Technology Comparison
Available Performance
Lead Acid
Battery
Ultracapacitor
Conventional Capacitor
Charge Time
1 to 5 hours
0.3 to 30 seconds
10-3 to 10-6 seconds
Discharge Time
0.3 to 3 hours
0.3 to 30 seconds
10-3 to 10-6 seconds
Energy (Wh/kg)
10 to 100
1 to 10
<0.1
Cycle Life
1000
>500000
>500000
Specific Power (W/kg)
<1000
<10000
<100000
Charge/discharge efficiency
0.7 to 0.85
0.85 to 0.98
>0.95
Technology Comparison
1000
Fuel Cells
10h
100
Energy Density/[Wh/kg]
0,1h
1h
36sec
LiBattery
Lead Acid
Battery
10
Ni/Cd
3,6sec
U/C
Double-Layer Capacitors
1
36msec
0,1
Al-Elco
0,36sec
0,01
10
100
1000
Power Density/[W/kg]
10000
Ultracapacitor World Market
Consumer Products
Industrial
Transportation
Car Audio
Remote Monitoring
Hybrid Bus/Truck
PDA
Handheld
Instrumentation
Engine Starting
Toys
Short term Back-up
Power
Light Hybrid
Memory Backup
Automation/Robotics
Local Power
Rail
Markets and Applications:
Consumer Electronics
Market needs include:
Miniaturization
Burst-mode
transmission
Compatibility
Greater
with new/divergent designs
functionality due to merging of protocols
Markets and Applications:
Miniaturization
Requires smaller/more efficient devices
Burst Mode Transmission
Requires compatibility with lower voltage power supplies
Uses 1/2 voltage but requires at least 2 times current to
maintain same power output
Allows for lower cost primary batteries instead of
rechargeable batteries
Markets and Applications:
Ultracapacitor Benefits
Price/performance/size improvements
Allows batteries to be sized for energy requirements, not power
Allows use of alternative, less expensive chemistries
Extends device use time by up to 100%
Allows primary (non-rechargeable) batteries to be used for lower cost
and convenience
Allows smaller battery size while still meeting peak power requirements
PowerBurst Ultracapacitors:
Cells
Cylindrical radial leaded devices
0.5 Farad to 100 Farad, with other values on request
2.7 Volts
Drop-in replacement to Panasonic, Ness, and others
PowerBurst Ultracapacitors:
Modules
Maxwell parts inside PC5 and PC10 cells
Active or Passive balancing
5.0 Volts to 25 Volts standard & customs
U.S. design
production.
Custom circuits and packaging available
using PC or TPL cells.
and
prototyping,
Asian
Ultracapacitor Aging
Unlike batteries, ultracapacitors do not have hard endof-life criteria
Ultracapacitors degradation is apparent through a
gradual loss of capacitance and a gradual increase in
resistance
End of life is when the capacitance and resistance are out
of the application range, and this will differ depending
on the application.
Therefore, life prediction is easily done
UC Benefits Summary
Calendar life
Cycle life
Function of average voltage and temperature
Charge acceptance
Function of average voltage and temperature
Charge as fast as discharge, limited only by heating
Temperature
High temp; no thermal runaway
Low temp; -40°C
UC Benefits Summary
No fixed VOC
Control flexibility; context-dependent voltage is permitted
Power source voltage compatibility
Examples: Fuel cells, photovoltaics
No Vmin
Cell can be discharged to 0 Volts
Control safety: no over-discharge
Service safety
UC Benefits Summary
Cell voltage management
Only required to prevent individual cell over-voltage
State of charge and state of health
State of charge equals VOC
Dynamic measurements for C and EST equals state of health
No historical data required
Inventory Management Services
Warehousing and Material Management
N. America & Asia
Schedule Share, Demand Pull, Consignment, EDI
NPI facility in San Diego for quickturn custom modules.
Third Party warehousing
Customer specific programs tailored to individual needs