Transcript GHS og andre vigtige informationssystemer

CLP (Implementation of GHS in Europe)
Lars S. Rasmussen, [email protected]
(WATER ● ENVIRONMENT ● HEALTH)
The Wercs 2009 Global User Group
10-11 June 2009
The Desmond Hotel, Albany, NY
GHS world wide
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GHS = Globally Harmonised System
UN 2002
EU, USA, Canada and transportation of dangerous goods
Harmonised criteria for classification and labelling
Facilitate worldwide trade
Reduce animal testing
Building blocks
GHS in EU
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Implemented as the CLP-regulation (1272/2008)
Adopted by the Council 18 November 2008
Into force 20 january 2009
Replaces Dangerous Substances Directive and Dangerous
Preparations Directive 1 June 2015
Classification – Before CLP
HEALTH
Very Toxic
Toxic
Harmful
Irritating
Corrosive
Sensitisation
CMR
PHYSICAL/CHEMICAL
Explosive
Flammable
Oxidising
ENVIRONMENT
Acute toxicity
Chronic toxicity
Ozone layer
Others
Classification – CLP
HEALTH
Acute toxicity
Skin irritation
Eye damage/irritation
Corrosive
Sensitisation
CMR
STOT
Aspiration
PHYSICAL/CHEMICAL
ENVIRONMENT
Explosives
Acute toxicity
Flammable gases
Chronic toxicity
Flammable liquids
Ozone layer
Flammable solids
Oxidising gases
Oxidising liquids
Oxidising solids
Flammable aerosols
Gases under pressure
Self-reactive substances and mixtures
Pyrophoric liquids
Pyrophoric solids
Self-heating substances and mixtures
Flammable gases in contact with water
Organic peroxides
Corrosive to metals
Global GHS vs. EU CLP
Building blocks NOT implemented by the EU
Hazard class, Category
Example
Flammable liquid, cat. 4
Flash point 140-200 F
”Combustible liquid”
Acute toxicity, cat. 5
LD50 (oral)
2000-5000 mg/kg
Skin irritation, cat. 3
’Slightly skin irritant’
Aspiration toxicity, cat. 2
’Low risk of aspiration’
Acute aquatic tox, cat. 2+3
’Less than ”Very Toxic” ’
Building block added by EU:
Hazard class
Example
Danger to the Ozone-layer
’CFC-gasses’
(The old N;R59)
Hazard Pictograms
Hazard Pictograms
Health
Physical/
chemical
Environment
Hazard Statements
• H2xx for physical/chemical hazards
– E.g. H226: Flammable liquid and vapour
• H3xx for health hazards
– E.g. H315: Causes skin irritation
• H4xx for environmental hazards
– E.g. H400: Very toxic to aquatic life
• EUHxxx for supplemental EU-phrases
– E.g. EUH066: Repeated exposure may cause skin dryness or
cracking
Precautionary Statements
• P1XX General
– E.g. P102: Keep out of reach of children
• P2xx Prevention
– E.g. P222: Do not allow contact with air
• P3xx Response
– E.g. P314: Get medical advice/attention if you feel unwell
• P4xx Storage
– E.g. P402: Store in a dry place
• P5xx Disposal
– E.g. P501: Dispose of contents/container to …
Labelling
Company name
Address
Telephone
Irritant
Risk of serious damage to eyes.
Irritating to skin.
BASIC CLEANER
Contains: 5% or over but less than 15%: non-ionic
surfactants.
Keep out of the reach of children.
In case of contact with eyes, rinse immediately with
plenty of water and seek medical advice.
Wear eye/face protection.
If swallowed, seek medical advice immediately and
show this container or label.
Dispose of this material and its container to
hazardous or special waste collection point.
Labelling
Company name
Address
Telephone
BASIC CLEANER
Contains: Alcohols, C9-11, ethoxylated
DANGER
Causes serious eye damage.
Causes skin irritation.
Contains: 5% or over but less than 15%: non-ionic
surfactants.
Obtain special instructions before use.
Wear protective gloves and eye protection.
IF IN EYES: Rinse cautiously with water for several
minutes. Remove contact lenses, if
present and easy to do. Continue rinsing.
Dispose of contents/container to …
Transitional provisions – Substances
20 January 2009
1 June 2015
1 December 2010
Classification
Either
Labelling
Classification
Or
Labelling
DSD*
DSD and CLP
CLP
DSD
CLP
CLP
DSD and CLP
DSD and CLP
CLP
CLP
CLP
CLP
*DSD = Dangerous Substance Directive 67/548/EEC
Substances classified in accordance with DSD and already
placed on the market before 1 December 2010 are not
required to be relabelled in accordance with CLP until 1
December 2012
Transitional provisions - Mixtures
20 January 2009
1 June 2015
1 December 2010
Classification
Either
Labelling
Classification
Or
Labelling
DPD*
DPD
CLP
DPD
DPD
CLP
DPD and CLP
DPD and CLP
CLP
CLP
CLP
CLP
*DPD = Dangerous Preparations Directive 1999/45/EC
Mixtures classified in accordance with DPD and already placed
on the market before 1 June 2015 are not required to be
relabelled in accordance with CLP until 1 June 2017
Translation table
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Substances classified before 1 December 2010
Mixtures classified before 1 June 2015
Translation table, Annex VII
Translation of health and environmental hazard
Translation of some physical/chemical hazards
Classification
under
directive
67/548/EEC
Physical
state of the
substance
when
relevant
E;R2
Fx;R12
Classification under CLP
Hazard Class-andCategory
Hazard
statement
No direct translation possible.
Liquid
Flam. Liq. 1
H224
Xn;R22
Acute Tox. 4
H302
Xi;R41
Eye Dam. 1
H318
N;R51/53
Aquatic Chronic 2
H411
Safety Data Sheet – Mixture before CLP
Safety Data Sheet – Mixture CLP 2010-2015
Safety Data Sheet – Mixture CLP after 2015
Obligations and tasks
• Importers, manufacturers of substances
– Re-classify no later than 1 December 2010
– Re-label no later than 1 December 2010 (2012)
– Notification to Classification and Labelling Inventory
– Update Safety Data Sheets
• Formulators
– Re-classify no later than 1 June 2015
– Re-label no later than 1 June 2015 (2017)
– Update Safety Data Sheets
• End users
– Adjust Work Place Instructions
– Adjust company chemicals policy
What do we do now?
 Define roles and obligations
 Define needs for training
 Define needs for update of
IT-systems
 Check legislation outside EU
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Lars S. Rasmussen, [email protected]
(WATER ● ENVIRONMENT ● HEALTH)
The Wercs 2009 Global User Group
10-11 June 2009
The Desmond Hotel, Albany, NY