Transcript 23_Air

Announcements – Oct 25
Test results are in.
CNN
Booming China's acid rain 'out of control'
November 30, 2004
China's explosive economic growth is outpacing
environmental protection efforts, leaving the country
awash in "out of control" acid rain. Acid rain fell on more
than 250 cities nationwide and caused direct annual economic
losses of $13.3 billion, equal to nearly three percent of the
country's gross domestic product. Two major causes were the
rapidly growing number of cars and increasing consumption of
cheap, abundant coal as the country struggles to cope with
energy shortages and meet power demand. China is the
world's largest source of soot and sulphur dioxide (SO2)
emissions from coal, which fires three-quarters of the country's
power plants.
Third of China 'hit by acid rain'
Sunday, 27 August 2006
One third of China is suffering from acid rain caused by
rapid industrial growth, an official report quoted by the
state media says.
Pollution levels have risen and air quality has
deteriorated, the report found. This comes despite a
pledge by the authorities to clean up the air.
CNN, November 16, 2004
Study links smog increase, urban deaths
CHICAGO, Illinois (Reuters) -- Increases in air pollution
caused by cars, power plants and industry can be
directly linked to higher death rates in U.S. cities.
Reducing such ozone pollution by about 35 percent on any
given day could save about 4,000 lives a year across the
country. The conclusion came from a look at 95 urban areas
where about 40 percent of the U.S. population lives,
comparing spikes in ozone pollution there with death rates
from 1987 to 2000. Ground-level ozone typically increases
when temperatures rise. While short-term increases have
been recognized as causing jumps in hospital admissions,
this study provides strong evidence of short-term effects of
ozone on mortality," said Francesca Dominici, an author of
the study.
Air Quality I
Lecture Objectives:
1) What are the major types and sources of
airborne pollutants?
2) What are the issues with ozone?
3) Has the Clean Air Act been effective?
Atmosphere
Atmosphere - air above the earth
78% nitrogen, 21% oxygen, 1% carbon
dioxide, water, other gases
Atmosphere
Divided into four zones: Troposphere, Stratosphere,
Mesosphere, Thermosphere
Decrease in
density further
from Earth
Troposphere
is where
weather takes
place
Stratosphere
contains most
of the ozone
Atmosphere
 Airborne particles mix, dilute, but remain in
atmosphere
 Accumulate in direction of winds
Can lead to
health problems

Asthma
 Adults with
asthma: 14
million (6.9%)
(2001)
 Children with
asthma: 6.3
million (8.7%)
(2001)
 Number of
deaths: 4,269
(2001)
http://www.cdc.gov/nceh/airpollution/about.htm
Air pollutants
Primary air pollutants
 Materials
that when released pose health
risks in their unmodified forms
Secondary air pollutants
 Primary
pollutants interact with one
another, sunlight, or natural gases to
produce new, harmful compounds
Primary Air Pollutants
Five major materials released directly into
the atmosphere in unmodified forms.
 Carbon
monoxide
 Hydrocarbons
 Particulate matter (2.5 mm and 10 mm)
 Sulfur dioxide
 Nitrogen oxides
189 substances are regulated under the
Clean Air Act
Carbon Monoxide (CO)
Produced by burning of organic material
(coal, gas, wood, trash, etc.)
Automobiles biggest source (80%)
 Decreases
because of fuel efficiency, catalytic
converters
 Offset by increase in number of cars, time spent
driving
Cigarette smoke another major source
Carbon Monoxide (CO)
 Toxic because binds
to hemoglobin,
reduces oxygen in
blood
 Not a persistent
pollutant, combines
with oxygen to form
CO2
 Most communities
now meet EPA
standards, but rush
hour traffic can
produce high CO
levels
Hydrocarbons (HC)
 Hydrocarbons - organic compounds with hydrogen,
carbon
 From incomplete burning or evaporated from fuel
supplies
 Major source is automobiles, but some from industry
 Contribute to smog
 Improvements in engine design have helped reduce
Particulates
 Particulates - small pieces of
solid materials and liquid
droplets (2.5 mm and 10 mm)
 Examples: ash from fires,
asbestos from brakes and
insulation, dust
 Easily noticed: e.g.
smokestacks

More attention, more
regulation
Particulates
 Can accumulate in lungs and interfere with the ability
of lungs to exchange gases.
 Some particulates are known carcinogens
 Those working in dusty conditions at highest risk (e.g.,
miners)
 pollution decreased 88% from 1970 - 2000
Sulfur Dioxide (SO2)
 Produced by burning sulfur
containing fossil fuels (coal, oil)
 Coal-burning power plants major
source
 Reacts in atmosphere to
produce acids
 One of the major components of
acid rain
Sulfur Dioxide (SO2)
When inhaled, can be very corrosive to lung
tissue
London
 1306
banned burning of sea coal
 1952 “killer fog”: 4,000 people died in 4 weeks

tied to sulfur compounds in smog
Nitrogen Oxides (NO, NO2)
 Produced from burning of
fossil fuels
 Contributes to acid rain,
smog
 Automobile engine main
source
 New engine technology has
helped reduce, but many
more cars
Acid Rain
 Sulfur dioxides and Nitrogen oxides combine with
water in the atmosphere to form sulfuric acid and
nitric acid
 The pollutants remain airborne for ~1-3 days and
travel 250-750 miles
 Combine with water in the atmosphere, fall back
as rain, snow, etc. – water with pH more acidic
than normal rainfall.
 US and Canadian governments officially
recognized effects in 1986
Effects of Acid Rain
Can degrade buildings and monuments
made of limestone
Effects of Acid Rain
Can acidify freshwater lakes (pH<4.7)
 Disrupt
physiological processes
 Release of toxic compounds normally bound to
soil (e.g. aluminum)
 Inhibition of nitrification, build up of ammonia
 Causes loss of game fish & other desirable
species
25,000 lakes in N. America altered by
acidification
Midwest lakes often on limestone, which
neutralizes acids
Photochemical Smog
Photochemical smog – secondary pollutants
formed by reaction of nitrogen oxides and
HC with sunlight
Includes ozone (O3)
 destroys
chlorophyll, injures lung tissue
 ground-level ozone is “bad ozone”
Photochemical Smog
 Biggest problems in
cities, mountains can
make it even worse
 Mountain ranges, wind
directions lead to
thermal inversions
when cool air is
trapped below layer of
warm air
 pollutants accumulate,
aren’t released to
upper atmosphere

http://www.epa.gov/airnow/ozone.html
Hazardous Air Pollutants
Hazardous Air Pollutants (HAP) are
compounds that can harm human health or
damage the environment.
Some released from consumer activities.
 Benzene
escapes during automobile refilling.
Most released from manufacturing
 Toxic
chemicals released from smelters
 Chemical and petroleum industry are primary
sources
Indoor Air Pollution
 In U.S., 90% of time spent
indoors; inside air often
more polluted than outside
air
 Problems with weatherized
building: little air exchange
 Asbestos, carbon
monoxide, formaldehyde,
lead, pollen, dust, smoking
 Causes diseases:
emphysema, heart
attacks, strokes, lung
cancers
Other Air Quality Issues
 Ozone Depletion
 Ozone in the
stratosphere is
“good ozone”

Shields us from
harmful ultraviolet
light

Skin cancer and
cataracts
Chlorofluorocarbons
 Used as refrigerants, cleaning solvents, propellants
 1970s – discovery that average concentrations of
Ozone in the stratosphere were declining
 UV radiation breaks down CFC molecules, releasing
atomic chlorine.


A free Chlorine atom reacts with an ozone molecule,
converting it from O3 to O2.
One chlorine atom can break apart more than 100,000
ozone molecules.
Chlorofluorocarbons
 CFCs take 10-20 years to make it into the
stratosphere.
 Can react with ozone for up to 120 years.
 1970s – CFCs as propellants in spay cans banned
in US
 1987 – Montreal Protocol
 No increase in CFC production
 50% reduction of production by 2000
 1991 – DuPont announced new refrigerant
 1996 – US stopped producing CFCs
Control of Air Pollution
Different Approaches
 Regulations
on auto industry
 Fines to enforce bans
 Switch from high sulfur coal to low sulfur coal
 Switch to oil, gas, wind, solar, nuclear power
 “Scrubbers” on smoke stacks to remove sulfur
after use

expensive -- $200 million per power plant
Much of regulation done under Clean Air Act
Clean Air Act (1970, 1977, 1990)
Control
requirements the federal government
implements and states administer
All sources subject to ambient air quality regulation
(NAAQS)
New sources subject to more stringent controls
Hazardous pollutants and visibility reducing
emissions regulated
August 2003 changes reduce control

no pollution control devices if “routine maintenance”
repairs are < 20% of the replacement value of the
entire process unit
Clean Air Act
 Since Clean Air Act passage, EPA reports air
pollution cut by 1/3 and acid rain cut by 25%.
 EPA estimates human health, welfare, and
environmental benefits have outweighed costs by
40 to 1.
 Old coal-fired power plants and SUVs, diesel
trucks and buses are still major problems
Improvement in Air Quality



4/5 primary air
pollutants
decreased since
1970
Nitrogen oxides per
vehicle down, but
overall emissions
increased due to
larger number of
cars
Lead emissions way
down after switch to
unleaded gasoline
Points to know – Nov 29
1) Know the types and proportions of the gases that make up
the atmosphere. In which zone of the atmosphere does
weather take place? Which contains ozone?
2) Distinguish between primary and secondary air pollutants.
What are the 5 major primary air pollutants, where do they
come from, and what problems do each cause?
3) What is photochemical smog, and how do thermal
inversions contribute to the problem?
4) Why should we be concerned with indoor air pollution?
5) Distinguish between “bad” ozone and “good” ozone. What
is causing depletion of the “good” ozone?
6) What does the Clean Air Act regulate, and how successful
has it been?