Fuel cells - The Toppers Way

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Transcript Fuel cells - The Toppers Way

Fuel cell
Types of fuel cell
• Fuel cells are classified primarily by the kind of
electrolyte they employ. This determines the
kind of chemical reactions that take place in the
cell, the kind of catalysts required, the
temperature range in which the cell operates,
the fuel required, and other factors. These
characteristics, in turn, affect the applications for
which these cells are most suitable. There are
several types of fuel cells currently under
development, each with its own advantages,
limitations, and potential applications. A few of
the most promising types include
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Polymer Electrolyte Membrane (PEM)
Phosphoric Acid
Direct Methanol
Alkaline
Molten Carbonate
Solid Oxide
Regenerative (Reversible)
Fuel Cell Comparisons
Electrochemical reactions of the Fuel Cell types
Polymer Electrolyte Membrane Fuel Cell
• Polymer electrolyte membrane (PEM) fuel cells—also
called proton exchange membrane fuel cells—
• deliver high power density and offer the advantages of
low weight and volume, compared to other fuel cells.
• PEM fuel cells use a solid polymer as an electrolyte and
porous carbon electrodes containing a platinum catalyst.
• They need only hydrogen, oxygen from the air, and
water to operate and do not require corrosive fluids like
some fuel cells.
• They are typically fueled with pure hydrogen supplied
from storage tanks or onboard reformers.
PEM FUEL CELL
Electrical current
e-
eWater and
Heat out
Excess fuel
out
e-
H2O
e-
H+
H2O
e-
H+
O2
H2
Fuel in
H+
Air in
Anode
Electrolyte Cathode
Alkaline Fuel Cell
• Alkaline fuel cells (AFCs) were one of the first fuel cell
technologies developed, and they were the first type
widely used in the U.S. space program to produce
electrical energy and water onboard spacecraft.
• These fuel cells use a solution of potassium hydroxide in
water as the electrolyte and can use a variety of nonprecious metals as a catalyst at the anode and cathode.
High-temperature AFCs operate at temperatures
between 100ºC and 250ºC (212ºF and 482ºF). However,
more-recent AFC designs operate at lower temperatures
of roughly 23ºC to 70ºC (74ºF to 158ºF).
• AFCs are high-performance fuel cells due to the rate at
which chemical reactions take place in the cell. They are
also very efficient, reaching efficiencies of 60 percent in
space applications.
ALKALINE FUEL CELL
Electrical current
e-
e-
Hydrogen
in
H2
Oxygen in
O2
ee-
eOHe-
Water and
Heat out
eAir in
Anode
Electrolyte Cathode