Transcript The Atom

The Atom
You think you know,
but do you???

Objectives
• Understand the models of Democritus,
Dalton, Thomson, Rutherford and Chadwick
• Compare and contrast the atomic models of
Democritus and Dalton
• Define an atom
• Distinguish between the subatomic particles
in terms of relative charge and mass
• Describe the structure of the nuclear atom,
including the locations of subatomic particles
There are a lot of depictions out there!
Which are correct?
Video: Nova Atoms Podcast
Definition of an Atom
• Smallest particle of an
element that retains the
properties of that
element
• All matter is made of
atoms
History of the Atom
• Democritus, 400 B.C.
– Greek philosopher
– Universe is made of invisible units
called atomos
– Matter is predominantly empty space
– Atoms differ in their size, shape and
movement
– Changes in matter result from changes
in groupings of atoms, and not
changes in the atoms themselves
Atom is derived
from the Greek
word meaning
“unable to be
divided”
DEMOCRITUS’ ATOM (400 BC)
WOULD HAVE LOOKED LIKE THIS:
(draw it!)
DEMOCRITUS’ ATOM (400 BC)
WOULD HAVE LOOKED LIKE THIS:
History of the Atom
• John Dalton, 1808
– English schoolteacher
– Atomic Theory built on Democritus’ Theory of Atomism
• Every element is made of tiny particles that cannot be
subdivided (atoms)
• Atoms of the same element are identical
• Atoms cannot be created, divided, or destroyed
• Atoms combine in whole number ratios to form
molecules
• Chemical reactions are atoms being separated,
combined, or rearranged
DALTON’S ATOM (1808) WOULD
HAVE LOOKED LIKE THIS:
DALTON’S ATOM (1808) WOULD
HAVE LOOKED LIKE THIS:
Atoms are particles of specific elements.
J.J. Thomson, 1897
– Found that all matter contained negative particles
– Cathode Ray Tube experiments
William Crookes
pioneered cathode ray
tube design
Thomson investigated
properties of the rays in detail
Cathode Ray Tube Experiment
It did not matter what
element he got the cathode
ray tube from; the cathode
rays were identical every time.
Open file: Cathode Ray Tube.flv
http://www.chem.uiuc.edu/clcwebsite/video/Cath.mov
Thomson’s Model
•Found the mass of an electron by passing electricity
through gases
•Mass of an electron was about 1/2000th that of a
hydrogen atom
•Contradicted Dalton – Atoms could be divided
•Attempted to explain why matter is not always
charged
THOMSON’S ATOM (1904) WOULD
HAVE LOOKED LIKE THIS:
THOMSON’S ATOM (1904) WOULD
HAVE LOOKED LIKE THIS:
Plum Pudding Model:
+
negative particles embedded
in a base of positive charges
to form uncharges atoms.
(this accounts for the fact that
matter is usually neutral)
Thomson’s Plum Pudding Model
Ernest Rutherford, 1909
• Gold foil experiment
Video: Gold foil experiment
reenactment!
Open file: gold foil reenactment.mp4
RUTHERFORD’S ATOM (1909)
WOULD HAVE LOOKED LIKE THIS:
RUTHERFORD’S ATOM (1909)
WOULD HAVE LOOKED LIKE THIS:
The Nuclear Atom:
electron area with
tiny, dense, positive
nucleus; mostly
empty space
James Chadwick, 1932
• A student of Rutherford
• “extra mass” problem of
isotopes…
CHADWICK’S ATOM WOULD HAVE
LOOKED LIKE THIS:
Why were these last particles so tough to detect???
CHADWICK’S ATOM WOULD HAVE
LOOKED LIKE THIS:
The Nuclear Atom:
electron area with
tiny, dense, positive
nucleus; nucleus
includes neutrons,
atomic number equals
number of protons,
mostly empty space
Disclaimer….