Transcript Slide 1
Multipollutant Air Quality Management:
A Critical Review
George M. Hidy
William T. Pennell
A&WMA 103rd Annual Conference and Exhibition
Calgary, Alberta, Canada
June 23,2010
Introduction and Overview
Motivation:
2004 NRC Assessment
Air Quality Management in the United States
--NARSTO evaluated and extended the concept for
North America
Current practice constrains our ability to meet
future challenges:
• Increasingly strict ambient standards
• Health effects of air toxics—integrated with criteria
pollutants
• Apparent lack of risk thresholds
• Environmental justice and “hot-spots”
• Ecosystem effects
• Regional influence and long-range transport
• Climate change
System could evolve to one that strives to-• Identify the most significant cumulative exposures, risks,
and uncertainties based on pollutant mixtures.
• Take a multipollutant approach to controlling emissions
that pose the most significant risks
• Take an airshed-based approach optimizing pollutant
reductions to minimize exposure risk to multipollutants
arising from local, regional, national, and international
sources
• Emphasize results over process, create a system for
evaluating the effectiveness of control measures, and
dynamically adjust and correct actions as they are
implemented
Charge to Assessment Team
• Assess the state of knowledge and the
multipollutant assessment tools for achieving a
risk-based air quality management approach that
incorporates means for assessing the
effectiveness of management actions
(accountability)
• Provide recommendations for enhancement of
capabilities and knowledge needing improvement
Assessment Chairs and Expertise
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George Hidy (Envair/Aerochem)
Jeff Brook (Environment Canada)
Ken Demerjian (State University of New York at Albany)
Luisa Molina (MIT and Molina Center for Energy and the
Environment)
• Rich Scheffe (EPA)
• Bill Pennell (NARSTO -ex-officio)
• A large group of contributors in the relevant sciences.
Approach
• Query health and ecosystem effects scientists
regarding their information needs for risk
reduction from multipollutant exposure
– Vital information for estimating exposure and dose
– Improved effects exposure-response; especially the
effects of exposure to pollutant mixtures
• Assess the ability of the atmosphericenvironmental sciences to meet these needs
– Existing resources
– Improved methods (chemical characterization, modeling
and monitoring) for assessing exposure
– Improved information on emissions and atmospheric
composition at point of exposure
Features of Risk- and Results-Based Air Quality
Management
• Administrative coordination
– All air pollutants and climate-forcing agents considered in
concert
– Reviews of standards coordinated and placed on compatible
schedules
– Plans for achieving goals coordinated
• Risk-based decision making
– Priority on reducing exposures that represent the greatest
risks
• Accountability
Transitioning to a Risk- and Results-Based
Approach
• Level 1: focus on attainment of individual ambient
standards
• Level 2: attainment of individual standards, but with
increasing attention to co-benefits from coordinated
emissions reductions
• Level 3: decisions based on achieving greatest risk
reduction based on single-pollutant exposure-doseresponse relationships
• Level 4: decisions based on achieving greatest risk
reduction based on multipollutant exposure-doseresponse relationships
Where Are We Now?
• Level 2 is clearly achievable -- given appropriate
planning and resources
• Level 3 is attainable given significant
improvements in exposure characterization, but
determination of relative risk is problematic
unless there are significant differences pollutant
exposure and potency
• Attaining Level 4 will require substantial
advances in our understanding of the
consequences of exposure to multiple pollutants
and our ability to simplify multipollutant exposure
assessment
Accounting for Problems of “Global” Change
Future air quality management could be complicated by
three global-scale influences
• Large -scale Transport of long-lived pollutants or pollutant
precursors resulting from increased global emissions
• Changes in emissions resulting from actions taken to mitigate
anthropogenic climate change, including substitution of
technologies
• Changes in atmospheric chemistry, biogenic emissions, and
meteorological conditions resulting from climate change—
climate change increasingly included in pollutant regulation?
These factors could affect strategies for managing air
quality, but current estimates of impacts are “small”
and extend to a long term (> 50 years).
The “Climate Penalty”
Tools and Priorities
Management
Options
(Policy)
Emissions
Risk
Characterization
Valuation
Ecosystem
Exposure
Ecosystem
Effects
Air Quality
Human
Exposure
Global Change
Human Health
Effects
Examples
The Toolbox for Multipollutant Strategies
• Tools to support multipollutant AQ strategies are well
known with understanding of –
– Atmospheric Physicochemical Processes
• Multipollutants derive from sources and atmospheric chemistry
– Measurements of Ambient Concentrations and Exposure
Estimation
• What’s there is fundamental! Criteria and Toxics
– Emissions Characterization
• Primary sources –magnitude, location, reactivity and futures
– System or Air Quality Modeling
• Present and future space and time
– Linking Exposure to Effects
• Exposure (Concentration) and Response Humans and
Ecosystems
Integrating Complexity for Relative Risk
Environmental Variables:
Solar Radiation, Temperature,
Relative Humidity
Light Absorbing
Photolytic
CP – HAPS
Precursor
Phase: Gas/Aerosol
Targeted
Functional Groups
Thermal Dissociation
Particle Size
Water Solubility
Chemical Lifetime
Reactivity
Analysis of Relative Risk –
Priority Setting
• The Current Approach Deals with Pollutants Separately.
– Formal Risk Analysis Methods Exist, but are Data Limited.
• A Risk-Based Framework Needs to be Able to Differentiate
Risks for Priority Setting.
• What Are the Criteria?
– Population vs. Individual Risk
– Cost and Benefit
• What’s Missing?
– Dose-Response of mixtures?
– Critical Elements—Toxicity and Concentration or Exposure?
• Are There Practical Measures for Risk Priorities Within the
Present Regulatory Frameworks?
– Some Demonstrations Focused on Cost-Benefit
Accountability is Important
Parallelism Between Risk Analysis, AQ Management and
Accountability
Paradigm
Goal Setting
Emissions
Strategy
Emiss. Inv.
Exposure
Audit Action
Emiss. Change
Model exposure
Effects
Ambient Measure
Effects
Exposure
Effects
How Far Can We Take Accountability
• Accountability is a Sequence of Assessment
Beginning with Emissions, Tracing through
Ambient Exposure Conditions to health or
Ecological Response
• Do Changes in Emissions Result in
Improvements in Public Health?
• Examples can be extracted from Records of
Progress.
– Ozone and Oxidants
– Particles
– HAPs, including Mercury
Trends in O3 –Los Angeles
Trends in Ambient Ozone
100
900
90
800
80
700
70
600
60
500
50
400
40
300
30
200
20
100
10
0
0
1995 1996 1997 1998 1999 2000 2001 2002 2003 2004 2005 2006 2007 2008 2009
Year
Mean Annual 4th Max O3
EGU NOx Emissions
EGU NOx Emissions (1000 tons per year)
Mean Annual 4th Highest O3 (ppbv)
Regional O3 (AL,GA,MS, FL) Don’t Follow NOx Emissions or
NMHC Emissions Changes
The Case of Particulate Matter
• Trends in Emissions and
Ambient Concentration
• Outdoor Concentrations
are exposure
– Exposure complexity
– Some PM is IndoorOutdoor
• Some PM is Not
• Assume Outdoor a
Surrogate!
• Health Effects and PMx
– Intervention Experiments
– Historical Health Change
PM Health Effects—Response to Change
• Accountability—The End Game
• Intervention Studies
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A Series of Studies
Utah Steel Mill Shutdown (Pope et al, 1989;Ghio, 2004)
U. S. Southwest- 1960s Smelter Strike (Pope et al., 2007)
Hong Kong Fuel Switch (Hedley et al., 2002)
Dublin Coal Use (Clancy et al., 2002)
• Long Term Changes with Ambient Air Quality
– Reanalysis of the 6 Cities Study (Laden et al., 2006)
– PM2.5 and Life Expectancy (Pope et al., 2009)
Opportunities for Multipollutant
Management
• Working within the Current Regulations
– Streamlining Administrative Direction, including Adjusting
Parallel Schedules for Implementing Emission Reductions.
– Expand Knowledge of Emissions and Air Chemistry to
Integrate Criteria Pollutants and Air Toxics.
– Use Risk-Based Goal Setting--Support with More Systematic
Concentration --Response Portfolio.
– Encourage Prescription of Accountability Chain in Regulatory
Process.
– Incorporate Feedback from Accountability Analyses into
Planning and Implementing Strategies, including Progressive
Changes.
For the Future
• Develop a Framework for Grouping Pollutants within
Common sources, Chemistry and Biological Response for
Addressing Strategies.
• Test Concepts for Risk Prioritization and Adopt These in
Complex Emission Reduction Strategies.
• Establish Refined Health and Ecological Effects Programs
to Address Relative Risk.
• Explore Improving Opportunities to Obtain Management
Relevant Feedback from the Accountability Chain.
• Review Monitoring and Measurement Programs to Estimate
Their Effectiveness in Providing Multipollutant
Characterization Beyond Regulated Pollutants.