Transcript Document

From Nano to Global:
Materials Approaches
to Climate and Energy
Transatlantic Science Week 2007: CLIMATE ACTION
October 22, 2007 – Carnegie Institution
Robert Hazen, Geophysical Laboratory
Pittsburgh, a Century Ago
Increased reliance on inexpensive fossil
fuels led to dramatic atmospheric effects.
Pittsburgh, ca.1900
Pittsburgh, a Century Ago
Andrew Carnegie’s steel empire contributed.
Pittsburgh, c. 1940
“The dirtiest and ugliest city in America.”
Pittsburgh
The problem has been alleviated by implementing
solutions from materials science.
Scrubbers
The Problem Today
Kavli Futures Symposium
“Merging bio and nano: towards cyborg cells”
11-15 June 2007, Ilulissat, Greenland
Greenland
Global climate change, triggered in part by
anthropogenic CO2 , is causing rapid and
dramatic changes to the ice fields.
2007 set a new melt record.
Retreat of the Jacobshaven glacier.
Greenland
Global climate change is also causing
rapid and dramatic changes to
species’ habitats and distributions.
Three Strategies
1. Generate less CO2.
2. Use less energy.
3. Remove CO2.
st
1
Strategy: Generate Less CO2
Biofuels
Hydrogen Production
and Storage
Biofuels
Employ new genetically engineered
crops, such as switch grass (carbon
neutral or negative).
Biofuels
Develop new enzymes to convert
cellulose to fuel.
Hydrogen Production
and Storage
Hydrogen generation by photodissociation of water.
Hydrogen storage in clathrates.
Water Dissociation
Passive process mimics plants:
2H2O + photons  O2 + 2H2
Martin Demuth,
Max Planck Inst.
Hydrogen Storage
in Clathrates
Methane Hydrate Clathrate
Hydrogen Storage
in Clathrates
H2(H2O)2
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1
Strategy: Generate Less CO2
We need fundamental advances in
materials science and technology.
Chris Somerville,
Carnegie, Plant Biology
Dave & Wendy Mao,
Carnegie, Geophysical Lab
nd
2
Strategy: Use Less Energy
Superconductors
High-Temperature Cuprates
Superconductors
Efficient magnet and motor technologies.
Superconductors
Efficient energy transmission and storage:
Nanocomposites for high Tc
Bi superconductor multi-filament tapes and wires.
2nd Strategy: Use Less Energy
We need fundamental advances
in materials science and technology.
Asle Sudbø,
Norwegian Univ. for
Science & Technology
Viktor Struzhkin,
Carnegie Inst.,
Geophysical Lab
rd
3
Strategy: Remove CO2
Artificial Photosynthesis
Deep CO2 Sequestration
Artificial Photosynthesis
Passive process mimics plants:
6CO2 + 6H2O + photons 
C6H12O6 + 6O2
Artificial Photosynthesis
Use supercritical CO2 (> 73 atm and 31ºC),
plus Rh catalyst, plus sunlight.
Etsuko Fujita, Brookhaven
Deep CO2 Sequestration
2.4 tons of CO2 from every ton of coal: The
world emits 26 gigatons of CO2 per year.
Deep CO2 Sequestration
Supercritical CO2 can be injected into old
wells , where it rises to the capstone and
slowly forms carbonate minerals.
Current capacity =
104 gigatons CO2
Deep CO2 Sequestration
Statoil platform
Deep CO2 Sequestration
The Deep Carbon Cycle
We need fundamental advances in
understanding Earth’s deep carbon cycle:
• What are carbon sources & sinks?
• What are carbon’s mass transport
mechanisms?
• Is there a deep source of organics?
• Did deep carbon play a role in life’s
origins?
CONCLUSIONS
Materials science and nanoscience
have the potential to contribute to
many outstanding global problems
related to energy and environment.
More fundamental research needs to
be done, especially on carbon-bearing
systems at extreme conditions.