Transcript Chapter 19: Oxidation-Reduction Reactions

•
Explain what must be conserved in
redox equations.
•
Balance redox equations by using the
half-reaction method.
•
The half-reaction method for
balancing redox equations consists of
seven steps:
›
1.
Write the formula equation if it is not
given in the problem. Then write the ionic
equation.
›
2.
Assign oxidation numbers. Delete
substances containing only elements that
do not change oxidation state.
›
3.
Write the half-reaction for oxidation.
• Balance the atoms.
• Balance the charge.
›
4.
Write the half-reaction for reduction.
• Balance the atoms.
• Balance the charge.
›
5.
Conserve charge by adjusting the
coefficients in front of the electrons so that the
number lost in oxidation equals the number
gained in reduction.
›
6.
Combine the half-reactions, and cancel
out anything common to both sides of the
equation.
›
7.
Combine ions to form the compounds
shown in the original formula equation. Check to
ensure that all other ions balance.
Sample
Problem A
A deep purple solution of potassium
permanganate is titrated with a colorless
solution of iron(II) sulfate and sulfuric
acid. The products are iron(III) sulfate,
manganese(II) sulfate, potassium sulfate,
and water—all of which are colorless.
Write a balanced equation for this
reaction.
 Sample
Problem A Solution
 1. Write the formula equation if it is not
given in the problem. Then write the
ionic equation.
KMnO4 + FeSO4 + H2SO4 
Fe2 (SO4 )3 + MnSO4 + K 2SO4 + H2O
K + + MnO4– +Fe2+ + SO24– + 2H+ + SO24– 
2Fe3+ + 3SO24– + Mn2+ + SO24– + 2K + + SO24– + H2O
Sample Problem A Solution,
continued
 2.
Assign oxidation numbers to each
element and ion. Delete substances
containing an element that does not
change oxidation state.
+7 – 2
+1
+
–
4
+2
K + MnO +Fe
+3
2Fe
3+
+6 – 2
+ 3SO
2+
2–
4
+6 – 2
+ SO
+2
+1
2–
4
2+
+ Mn
+6 – 2
2–
4
+
+ 2H + SO
+6 – 2
2–
4
+ SO
+1
+

+6 – 2
2–
4
+ 2K + SO
Only ions or molecules whose oxidation
numbers change are retained.
+7 – 2
–
4
+2
2+
MnO + Fe
+3
3+
+2
 Fe + Mn2+
+1 – 2
+ H2O
Sample Problem A Solution,
continued
 3.
Write the half-reaction for
oxidation. The iron shows the increase
in oxidation number. Therefore, it is
oxidized.
+2
+3
3+
Fe  Fe
2+
•
Balance the mass.
• The mass is already balanced.
•
Balance the charge.
+2
+3
3+
Fe2+  Fe + e–
Sample Problem A Solution,
continued
 4.
Write the half-reaction for
reduction. Manganese is reduced.
+7
+2
MnO4–  Mn2+
Balance the mass.
Water and hydrogen ions must be added to balance the
oxygen atoms in the permanganate ion.
+7
+2
MnO + 8H  Mn2+ + 4H2O
–
4
+
Balance the charge.
+7
+2
MnO4– + 8H+ + 5e–  Mn2+ + 4H2O
Sample Problem A Solution,
continued
 5.
Adjust the coefficients to
conserve charge.
e– lost in oxidation
1

–
e gained in reduction
5
5(Fe2+  Fe3+ + e – )
1(MnO4– + 8H+ + 5e–  Mn2+ + 4H2O)
Chapter 19
Section 2 Balancing Redox Equations
Half-Reaction Method, continued
 Sample
Problem A Solution,
continued
 6. Combine the half-reactions and
cancel.
Fe2+  Fe3+ + e–
MnO4– + 8H+ + 5e–  Mn2+ + 4H2O
MnO4– + 5Fe2+ + 8H+ + 5e–  Mn2+ + 5Fe3+ + 4H2O + 5e–
Chapter 19
Section 2 Balancing Redox Equations
Half-Reaction Method, continued
 Sample
Problem A Solution,
continued
 7. Combine ions to form compounds
2+
–
+
3+
2+
2(5Fe
+
MnO
+
8H

5Fe
+
Mn
+ 4H2O)
4
from the original
equation.
10Fe2+ + 2MnO4 + 16H+  10Fe3+ + 2Mn2+ + 8H2O
10FeSO4 + 2KMnO4 + 8H2 SO4 
5Fe2 (SO4 )3 + 2MnSO4 + K 2SO4 + 8H2O