Transcript food
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Management of
environmental contaminants
Description of the particularities of the environmental contaminants, mainly heavy
metals and persistent organic pollutants (dioxins and PCBs). Exchange of views and
revision of the current management measures in place both in the EU and Codex,
including food and feed, for environmental contaminants in all the fields of
competence involved.
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Content
• Environmental contaminants (natural)
- PAH*
- Heavy metals (Cd, Pb, Hg)
- Arsenic
• Persistent organic pollutants (chemical synthesis)
- Dioxins
- DL-PCBs
- NDL-PCBs
- Other POPs (PFOS & PFOA, BFRs)
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Heavy Metals
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Heavy metals
• Natural components of the Earth’s crust that
can be increased by human activity
(industry, agriculture)
• Foodstuffs are the main source of heavy
metals exposure for the general population
• Neither chemically nor biologically
biodegradable. They accumulate in the body
• No biological function (humans, animals).
Toxic to humans at certain levels
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Cadmium
• Example of how to manage environmental
contaminants
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Cadmium
• Natural component of the Earth’s crust that can be
increased by human activities (mining, paints,
batteries)
• IARC has classified cadmium as carcinogenic to
humans (category 1)
• Cadmium can accumulate inside the body and may
cause renal dysfunction and bone demineralisation
• Foodstuffs are the main source of cadmium
exposure for the non-smoking general population
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EFSA‘s Scientific Opinion on cadmium in
foodstuffs (2009)
• The mean exposure for adults across Europe is
close to, or slightly exceeding, the TWI
• High consumers (vegetarians, children, smokers
and people living in highly contaminated areas) may
exceed the TWI by about 2-fold
• EFSA concluded that the current exposure to Cd at
the population level should be reduced
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Source: http://www.efsa.europa.eu/en/scdocs/scdoc/980.htm
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Consumption
Level
Consumption
Cocoa
Crustaceans
Offal
Fungi
Oilseeds
Algae
Molluscs
Level
Cereals
Potatoes
Bread and rolls
Bakery products
Chocolate products
Leafy vegetables
HIGHER IMPACT ON
THE EXPOSURE
EXPOSURE
Cd level in
foodstuffs
Food
consumption
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ML
(ALARA)
5%
P95
X
Distribution of a certain contaminant in a foodstuff
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RISK
ASSESSMENT
RISK
MANAGEMENT
Revision of MLs
1881/2006
(lower)
EFSA 2009
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Persistent Organic
Pollutants (POPs)
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Vietnam, 1962-1971
2,4-D y 2,4,5-T
Herbicides
Carcinogen byproduct
2,3,7,8-TCDD
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What are they?
Accumulate
(C-H)n
Toxic
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General characteristics
• Resistant to
degradation:
• Photolytic
• Biological
• Chemical
• Low affinity for
polar
compounds
Stability
High
liposolubility
Bioaccumulation
Volatility
• Magnification
along the food
chain
• Travel long
distances
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Dioxins
• Not commercially produced
• Unknown utility (GOOD!)
• Undesired by-products of:
- Incineration of municipal waste
- Industry emissions (chemical, mining, metal and paper
industries)
- Synthesis of certain chemicals (pesticides or other chloride
substances)
- Emissions from energy generation/means of transportation
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Dioxins (cont’d)
• They remain as impurities or may be released to
the air
• 210 compounds
• Toxicity:
17 toxic (complex mixtures)
Acute effects:
Burns
Chloracne
Chronic effects:
Heart disease
Immunological disruption
Feminize babies
Cancer
• Exposure of humans mainly by food of animal origin
(fish, meat and milk products)
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PCBs
• Produced in the past as:
- Liquid insulating material (electric equipment, transformer
oils, dielectric fluids)
- Solvents for pesticides
- Flame-retardant materials
•Very high stability
•Low inflamability
•Low conductivity
• 209 congeners
• Complex mixtures
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PCBs (cont’d)
• Forbidden since the 80’
• Still released to the environment (improper disposal
or leaks)
• Co-occur in nature together with dioxins (same
toxicity and route of exposure)
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Difference between dioxins and PCBs?
Dioxins
PCBs
Non-intentional
by-products of a
series of chemical
and combustion
processes
Chemical products
produced
intentionally
(during 30’-70’)
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PCBs
Dioxin-like PCBs
Non-dioxin-like PCBs
• 12 toxic congeners
• ML in Regulation
1881/2006 (TEQs)
• ppb-ppt
• Same
distribution/toxicity
as dioxins
• 6 toxic congeners
• ML in Regulation
1881/2006 (no TEQs)
• ppm
• Neurotoxic
• Markers of the
presence of DL-PCBs
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MANAGEMENT MEASURES
FOR ENVIROMENTAL
CONTAMINANTS IN FOOD
AND FEED
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Human
activities
ENVIRONMENT
PLANTS, ANIMALS,
WATER
Industrial/transport emissions
Disposal of waste
Production, use or elimination of
certain substances
New chemicals
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FOOD/FEED
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Exchange of views
Your are the government of your country.
Based on the information given, your experiences and on
measures which may have already been taken in your
countries, we will discuss risk management measures to
reduce human exposure to environmental contaminants via
diet in the different fields involved.
Discussion in groups (5 minutes) and we will explore the
measures together.
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Maximum limits
REGULATION
1881/2006
FOOD
DIRECTIVE
2002/32
FEED
• Pb, Cd, Hg, As
• Dioxins and PCBs
• Undesirable
substances
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... but setting up MLs
• Costly
• Low efficacy
• Not possible to reduce/eliminate its content in
the food
• Rejection and destruction of whole lots
Need for Preventive Measures!
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Monitoring for POPs
• Recommendation 2006/794/EC on background
levels of dioxins, dioxin-like PCBs and non-dioxinlike PCBs in foodstuffs
• Recommendation 2013/711/EU on the reduction of
the presence of dioxins, furans and PCBs in feed
and food (action levels)
• Recommendation 2014/118/EU on BFRs in food
• Recommendation 2010/161/EU on PFOS in food
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Action levels vs MLs
ML
3 pg/g fat
Egg
Action Level
•
•
•
•
Lower than ML
Requires “action”-investigation
No withdrawal is needed
FBO self-control/official control
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1,75 pg/g fat
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Codes of practice for heavy metals
• Recommendation 2014/193 on the reduction of the
presence of cadmium in foodstuffs
• CAC/RCP 56-2004 on the prevention and reduction
of lead in foods
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Codes of practice for POPs
• CAC/RCP 62-2006 on prevention and reduction of
dioxins and dioxin-like PCB contamination in food
and feed
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Codes of practice for all chemicals
• CAC/RCP 49-2001 concerning source directed
measures to reduce contamination of foods with
chemicals
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Other measures for POPs
STOCKHOLM
CONVENTION
• Regulation 850/2004 on persistent organic
pollutants
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CONCLUSIONS:
• The most effective risk management measure to
reduce human exposure (general population) to
environmental contaminants is the establishment of
MLs
• However, this measure is very costly since the noncompliant foodstuff has to be destroyed
• Preventive measures are more useful, less costly
though they give results in the long term
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