Transcript Unit 7 web

7. Energy and Food
chapter 8
Energy = the ability to do work
A calorie is the amount of heat (or energy)
needed to raise the temperature of one gram
of water by one degree Celsius.
A kilocalorie (kcal) is 1000 calories.
joule is 0.24 calories.
A
Almost all of the chemical energy contained in
any substance is stored in its chemical bonds.
calorie
vs
kilocalorie
Bond Energy
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The E required to break a chemical bond or
The E released when the bond is formed
C-H ~ 100 kcal/mole; C-C ~ 90kcal /mole;
O-H~ 110 kcal/mole; C=O~ 170 kcal/mole
O=O ~118 kcal/mole
An exothermic reaction is a reaction that
releases heat as it proceeds .
exo
CH4 + 2O2
endo
CO2 + 2H2O + energy
An endothermic reaction is a reaction that
absorbs heat as it proceeds .
Why is this reaction exothermic?
• E required to break the bonds of reactants is 4 x CH bond E + 2 x (O=O) bond energy = 4 (100) +
(2 x118) = 636 kcal
• E liberated when bonds of products are formed = 2
x (C=O) bond Energy +4 x (O-H) bond E ie
(2x170) + 4 (110) = 780 kcal
• Thus Energy is released in this reaction: 780-636=
144 kcal/ mole of methane burned
FOOD = FUEL FOR THE HUMAN ENGINE
The Energy Equation
Energy In = Energy Out + Energy Stored
Metabolism is the combination of all chemical
reactions that take place in any living organisms.
1 Kilocalorie = 1 nutritional Calorie (Cal)
ENERGY IN: The Macronutrients
The macronutrients of our food are the three
major groups that make up the great bulk of
our food supply, the chemicals that serve as
the only source of energy for the human
machine .
Through the elegant, intertwined complex of
chemical reactions that constitute human
metabolism, the chemical energy of these
compounds becomes transformed into the human
energy of our lives .
The Macronutrients
fats and oils
carbohydrates
protein
Energy from Macronutrients
• From fat: 9 Calories per gram
• From protein: 4 Calories per gram
• From carbohydrate: 4 Calories per gram
Why do we get more calories from
fat than from carbs or protein?
• Fats contain long hydrocarbon chains in the
fatty acid part of the molecule
• More C-H bonds to be oxidized to Water
and CO2.
• Recall relatively high bond Energy in C=O
and O-H vs. C-C and C-H bonds (methane
combustion ).
Calories for Healthy Eating
• Recommended levels from macronutrients
• From carbohydrates (55%): 10% from
simple sugars (sucrose, glucose, fructose);
45% from complex carbohydrates (starch)
• From fat (30%): maximum 10% from
saturated fat, best from unsaturated
• From Protein (15%)
Some would disagree
• Atkins Diet : advocated as few calories as
possible from carbohydrates
• Theory (1972 book) was that sugars and
carbohydrates increase insulin levels and
facilitate fat storage
• Depriving the body of carbohydrates
facilitates fat burning and hence weight loss
Problems with the Atkins diet
• Too much saturated fat -> coronary disease
• Too little fibre, hence poor waste product
elimination and risk of kidney disease and
colon cancer
• Conclusion: Not a healthy alternative
• Expensive: Permitted foods were Atkins
Diet products
Atkins Diet products
North American Problems
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Too much simple sugar
Too much saturated fat
Too many calories!!
Not enough physical activity
Obesity is a major health issue
Micronutrients
• Food components such as Vitamins and
Minerals, which are required in relatively
small amounts for good health
• Not significant sources of calories
What is Junk Food?
• Food that supplies a large number of
calories but few Vitamins or Minerals
(Micronutrients)
• “Empty Calories” –ie. highly refined sugar
(Sucrose) –provides calories but no
micronutrients
“Empty”Calories from soft drinks
• Classic Coke 42 grams of sugar per 341 mL can
x4 Cal/gr= 168 Calories
• Diet Coke: no sugar, artificial sweeteners
(aspartame and potassium acesulfame) 0 Calories
(on can)
• Carbonated water, caramel flavor, caffeine,
phosphoric acid, citric acid, sodium benzoate, 0.1
gr of protein, so not quite 0 Cal.
Enzymes in Digestion
• Enzymes (bio-catalysts) help to break down
complex substances into simpler ones which
can be absorbed
• Need optimal pH-ie pepsin in the stomach
works best at pH near 2
• Suffix “ase” denotes an enzyme
Carbohydrase enzymes
• Amylase in saliva, breaks starch and
complex carbohydrates into maltose
• Maltase then breaks the maltose into
glucose
• Sucrase, lactase act on sucrose and lactose
breaking them down into simpler sugars
such as glucose and fructose
Protease enzymes
• Pepsins-secreted in stomach and pancreas to
help proteins break down into peptides and
eventually into amino acids
Lipases
• Secreted in pancreas and walls of the small
intestine
• Digest lipids (fats) and breaks them up into
fatty acids and glycerol
Digestion
ENERGY OUT
Exercise
Specific Dynamic Action
Basal Metabolism
Specific dynamic action, SDA, the energy
consumed in digesting and metabolizing food and
converting its energy for use in exercise and
basal metabolism.
It is the price we pay, in energy, for extracting
energy from food .
(~10% of the energy obtained from food)
ie. consume 2500Cal and use 250Cal for SDA
We can sense SDA in operation as we grow
warmer and find our heart beating a bit faster
after a meal. The warmth and higher pulse are
both signs that our body is working at digesting
the food and using up energy through SDA.
Drowsiness after a large meal comes from
the diversion of blood from the brain to the
digestive system. The body is working hard to
process all the fuel that’s just been brought in
and - first things first - digestion takes
momentary precedence over mental alertness.
After a great dinner!
Basal metabolism accounts for all the
work that goes on inside our bodies just
to keep us alive.
It is the energy expended as our heart
pumps, as our lungs expand and contract,
and as the liver, kidneys and other major
organs work to maintain life .
In a healthy adult the energy spent through
Basal Metabolism amounts to approximately
1 Calorie / hour / kg of body weight
Basal metabolism increases with any bodily
stress, desirable (eg. pregnancy or lactation) or
not (eg. illness).
Measured at rest, but awake, after a 12 hour fast
Calorie needs for inactive male
• For 70 kg (154lb) man; need 24 x 70= 1680
Cal per day for basal metabolism
• But also need additional amount for SDA
which is about 10% more. Thus ~ 1900
Cal/day total
Resting metabolism represents the
combination of basal metabolism and SDA.
Most of the energy coming directly from the food we
eat is spent on SDA and BM. The energy we use
for exercise comes largely from stored energy.
If the only metabolic energy available to us, or
our predecessors, were the energy from the
macronutrients of a recent meal - none of us
would be alive today.
Our vital organs would run out of energy between
meals, even as we sleep, if our body could not store
the excess fuel of each meal and then use that
stored fuel to provide a continuous supply of energy
between meals, as required.
Energy Availability & Storage
• Instant: blood sugar (Glucose) lasts ca. 30
minutes
• Short term Liver and muscles store
glycogen (about 2500 Calories) max 6-8
hours.
• Long term: fat is stored in adipose tissuecan last up to 35 days
Hitting the Wall
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Marathon runners use ~ 15Cal/minute
After 2.5 hours, use 150x 15=2250 Cal
Glycogen tank is empty!!
Need to consume short term E : glucose etc.
Fat metabolism is slow and thus of no use
as a short term E source
Energy Stored = Fat! (Adipose Tissue)
Adipose tissue stores
chemical energy at
~3500 Cal / lb
(~7700 Cal / kg)
Water content of adipose tissue
• Why only 7.7 Cal/gram stored in adipose
tissue if fat provides 9 Cal/gram?
• A: ~ 15% of adipose tissue is water
• Thus : 9- (.15x9) = 9- 1.35 =7.65 Cal/gram
But if we don’t ‘exercise’ enough then:
Energy In
X
SDA + BM + Energy Stored
and the energy/fat remains stored!
The evolution of man
• Sedentary lifestyle needs fewer calories
Daily Energy Needs According to
Physical Activity
Activity Level
Very light
Men
Women
Light
Men
Women
Moderate
Men
Women
Heavy
Men
Women
Factor
1.3
1.3
To estimate your energy needs ,
multiply your estimated BMR (10x your
weight in lbs.) by the factor listed in the
table that best represents your general
level of daily activity.
1.6
1.5
Very Light : mostly sitting and standing
activities
1.7
1.6
2.1
1.9
Light : mostly walking activities
Moderate : cycling, tennis, dancing
Heavy : heavy manual digging,
climbing, basketball, soccer
Typical 175 pounder
• Caloric requirement is 10x 175 x1.3 if
inactive, ie 2275 Calories per day.
• If you play for the Ottawa Senators, 175 x
10 x 2.1= 3675 Calories per day
• Females: a bit lower ca 1900 Cal/day
• Q: Do women have more efficient
metabolisms? A: yes! Women have less
muscle and more fat (on the average).
How many soft drinks per day?
• Recall max. 10% of Cal. from simple
sugars, so 10% of 2275 =227.5 Cal/
• Recall one can of regular Coke contains
over 160 Cal
• So, the answer is…………………..1 .
Calories from Alcohol
• 7 Calories per gram
• Thus in a 341mL can of normal beer (5 %),
assuming its density is 1 gram per mL
• Calories = .05 x 341 x 7 = 119.35
• A glass of wine or a shot (1.5 oz of liquor)
have about the same caloric content
• No nutrients, depresses CNS and is toxic to
liver
Recommended levels of alcohol
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Max. 2 drinks per day (male adult)
Max. 1 per day (adult female)
0 per day if pregnant or lactating!
0 per day if on certain medications
Moderation is KEY!!
Approximate Rates of Energy
Expenditure for a 70kg (154lb) Person
Calories Expended
Level
Very light
Light
Moderate
Heavy
Examples
Per Minute Per Hour
Sitting, reading, watching TV,
writing, driving
Slow walking, washing, shopping,light sports such as golf
Fast walking, heavy gardening,
moderate sports such as
bicycling, tennis, dancing
Vigorous work, sports such
as swimming, running,
basketball and football
1.0-2.5
60-150
2.5-5.0
150-300
5.0-7.5
300-450
7.5-12.0
450-720
Energy used in a Variety of Activities
Activity
Bicycling, 15 mph
Bicycling, 5mph
Chopping wood
Driving an automobile
Eating
Gardening, weeding
Listening to lecture
Pick and shovel work
Running 5 mph
Skiing, cross country
Swimming, pleasure
Tennis, (recreational/competitive)
Walking 3-5 mph
Walking up stairs
Energy (Cal/min)
12
5
7.5
2.8
1.5
5.6
1.7
6.7
10
9-17
6
7/11
5.6
10-18
DEMO: Energy from snack foods
• Potato is mostly carbohydrate-ie 4 Cal/gram
• But , if it is deep fried in fat, add 9 Cal per
gram of fat
• Burning potato chip: fat burns off
• Black residue is just Carbon
• Salt NaCl adds yellow colour to flame