Transcript Slide 1
Chapter 21
By: Vanessa LaTorre
The pH of Precipitation
Precipitation is naturally acidic – pH 5.2 to 5.6
Due to carbon dioxide in atmosphere
• Dissolves in water and forms carbonic acid
pH scale measures acidity or alkalinity
Scale from 0 to 14
pH 7 neutral, <7 acidic, >7 alkaline
Acid precipitation if pH level 5.0 or less
Formation of Acid Precipitation
Volcanic eruptions emit sulfur dioxide
With moisture in air forms sulfuric acid
Forest fires/lightning lower pH of precipitation
Release nitrogen oxide compounds
Mix with moisture in air
Forms nitric acid
Anthropogenic Gases
Combustion of fossil fuels:
Gasoline, coal, natural gas
Adds nitrogen oxides and sulfur dioxide to atmosphere
Trucks and automobiles get power from hydrocarbons
• Gasoline mixes with air and is ignited
• Burning of a substance is called combustion
• Forms nitrogen oxide compounds
Anthropogenic Gases (continued)
Coal is burned for energy
Contains sulfur
Combines with oxygen to form sulfur dioxide
Nitrogen oxides and sulfur dioxideanthropogenic gases
Means human created
Rise into atmosphere and combine with water
form nitric and sulfuric acids
Anthropogenic Gases (continued)
Acid deposition is different than acid
precipitation
When dry, nitrogen and sulfur deposited directly
Causes a reaction with surrounding environment
Leads to the formation of strong acids
Also caused by anthropogenic gases
Long-Distance Transport of
Acid-Causing Pollutants
Majority of sulfur dioxide comes from the
Midwest
90% of all acid precipitation and deposition
From sulfur dioxide
Because of prevailing winds west-east
Northeast receives greatest amount of acid
precipitation
Long-Distance Transport of AcidCausing Pollutants (continued)
When produced west of Appalachian
Mountains
Nitrogen oxides/sulfur dioxide rise into atm.
Mix with atmospheric moisture (water vapor)
Forms acid precipitation
By time reaches Appalachian Mountains
• pH is 4.3 to 4.5
Long-Distance Transport of AcidCausing Pollutants (continued)
Called long-distance transport of acid
precipitation
Similar process in Europe
Western Europe creates pollutants
Causes precipitation
Falls on eastern Europe
Effects of Acid Deposition on
Aquatic Ecosystems
Unpolluted ecosystems pH is 6.0 to 8.0
Lakes and ponds exposed experience
decreasing pH
Aquatic organisms die at pH 4.0 or lower
Acids that collect also leach heavy metals
Mercury, aluminum, and calcium
Absorbed by tissues of organisms
Cause adverse health effects
Effects of Acid Deposition on
Aquatic Ecosystems (continued)
Humans who eat these organisms are also
affected
Toxic metals build up in human tissue
Cause health problems
Worst effect in winter
Acidic snow accumulates
Spring thaw releases large amounts of acidic
water
Effects of Acid Deposition on
Aquatic Ecosystems (continued)
Acidic water enters nearby lakes and
streams
Causes acid shock
• Acidic water rapidly entering aquatic ecosystem
Most adult organisms can survive
Younger organisms and eggs are usually killed
Natural limestone rock outcrops buffer the acids
Effects of Acid Precipitation on
Terrestrial Ecosystems
Many plants and trees are stressed
Caused from acids burning leaves and stems
Leaves and stems exposed to disease
Causes them to loose water
Acids can leach important plant nutrients
Potassium, calcium, and magnesium
Other nutrients can be released causing damage
Effects of Acid Precipitation on
Terrestrial Ecosystems (continued)
Acid precipitation can kill off beneficial
organisms
Bacteria and fungi that add soil fertility
Can also inhibit germination of plant seeds
Directly affects agricultural production
Effects of Acid Deposition on Humans
Humans affected by acid precipitation and
deposition
Consume fish that live in acidic waters
May intake toxic heavy metals
Affects food production and forest products
• Timber pulp, and maple sugar
Can also cause respiratory illness
Irritation of eyes, nose, and throat
Effects of Acid Deposition
on Building Materials
Structures and building materials damaged
Weathering of concrete and stone is enhanced
Bridges, buildings, and concrete structures
• Slowly dissolved and weakened
Stone and brick broken down over time
Steel, iron, and copper are corroded
Paints, varnish, rubber, and ceramics damaged