Transcript Lecture1cdw

NATS 101
Lecture 1
Atmospheric Composition
100 km
100 km
C = 2pa
 4.084 x 104 km
Ratio: Height/ Length is 100/(4.084 x 104)
 2.45 x 10-3
- height of the atmosphere is extremely
small compared with its length
 air motions are primarily horizontal.
a  6500 km
 air motions are primarily horizontal
 very small vertical motions are very important,
e.g., they causing the development/inhibition of clouds.
Here are some of the characteristic features on thunderstorms.
The flat top forms when the updraft encounters the bottom of the
stratosphere
Some of the weather hazards associated with thunderstorms are heavy
rain and flooding, strong winds, and lightning
Composition of the atmosphere
1. Permanent gases
2. Variable gases
3. Aerosols
1. Permanent gases
stable concentration in the atmosphere.
• account for about 99% of the atmospheric mass
• occur in a constant proportion in the lowest ~80 km of the
atmosphere.
• although individual molecules exchange between the
atmosphere and Earth, the total concentration remains the
same  chemical homogeneity
• Lowest 80 km is called the Homosphere and is sometimes
considered to be the entire atmosphere.
• The atmosphere above this is called the Heterosphere.
Fill in the blank above with nitrogen
1. Permanent gases
N2 + O2 = 99% of atmospheric
volume below 80 km.
They are chemically active.
Ar, Ne, He, Xe < 1% and are
chemically inert.
** The residence time of a gas is the average time an individual molecule
remains in the atmosphere.
This is a list of the 5 most abundant gases in air
It includes permanent gases and a couple of the
variable gases
1. Permanent gases
Nitrogen:
• N2 is added and removed from the atmosphere very
slowly – long residence time** of ~42 million years.
• N2 is relatively unimportant for most meteorological and
climate processes
• some gases containing N are important to the Earth’s
climate such as NO2.
Oxygen:
• O2 is crucial to the existence of almost all forms of life
currently on the Earth. Its residence time is ~5000 years.
Most of the oxygen in air comes from plants
(photosynthesis)
2. Variable gases
distributions vary both in time and space.
• account for < 1% of the atmosphere below 80 km.
• some of these gases impact the behavior of the
atmosphere considerably.
H2O + CO2 + O3 = 0.296% of atmospheric volume.
Water Vapor (0.25%)
• water vapor varies considerably in both
space and time.
• Continually cycled between atmosphere
and earth by evaporation, condensation
and precipitation. (hydrologic cycle)
• Stores and releases large amounts of heat via evaporation
and condensation.
• Water vapor has a residence time of only 10 days.
• WV density is greatest at the surface, and decreases rapidly
with height.
• WV is extremely important for clouds
• WV absorbs radiant energy emitted from the Earth’s surface.
(Greenhouse gas)
I don’t think I mentioned this in class on Tuesday.
I’ll come back to it briefly on Thursday
Carbon Dioxide (0.036%)
• (CO2) is supplied to the atmosphere through plant and animal
respiration, through decay of organic material, volcanic
eruptions, and both natural and anthropogenic (human caused)
combustion.
• It is removed through photosynthesis, the process by which
green plants convert light energy to chemical energy. Oxygen is
released into the atmosphere as a by-product.
• CO2 has a residence time of ~150 yrs.
• It is an effective absorber of longwave radiation emitted from
the Earth’s surface. (Greenhouse gas)
• Its concentration in the atmosphere has increased ~18% since
1958.
Ozone (0.01%)
• (O3) is an unusual molecule made up of 3 Oxygen atoms. It
forms when individual O atoms collide with an O2 molecule and
exists in very small concentrations in the stratosphere (we’ll
define this a little later).
• O3 is vital for absorbing lethal UV radiation from the sun. As it
does this, it breaks down into its constituent components O + O2.
• Near the surface ozone is a pollutant, but exists there in
extremely small amounts.
3. Aerosols
• are small solid particles or liquid droplets (except water
particles) in the air.
• They are formed by both natural and anthropogenic means.
Aerosols typically have residence times of a few days to several
weeks.
• Apart from pollution, aerosols play an important role as
condensation nuclei, the core about which water can condense
in clouds.
• Formed from chemical reactions, wind-generated dust, volcanic
ejections, sea spray, and combustion (e.g., fine ash)
 removed from the atmosphere in precipitation.
Composition of the atmosphere - recap
1. Permanent gases
Name two permanent gases
2. Variable gases
Name two variable gases
3. Aerosols
Name two ways aerosols form
Vertical Structure of the atmosphere
1. Density
2. Pressure
3. Temperature
We’ll start this section on Thursday