Transcript sclecture7

Type I and Type II superconductivity
Using the first Ginzburg Landau equation, and limiting the analysis to first order in
 (which is already small close to the transition) we have
1
i  e * A 2   
2m *
This is a well known quantum mechanical equation describing the motion of a
charged particle, e*, in a magnetic field
The lowest eigenvalue of this Schroedinger equation is
Eo  21 c
c is the cyclotron frequency
c  B
e*
m*
e * B
2m *
Recognising that we have a non zero solution for , hence superconductivity
when B<Bc2, we obtain from the Schroedinger equation:
so
Eo 
e * Bc 2
 
2m *
Lecture 7
Superconductivity and Superfluidity
Type I and Type II superconductivity
We have
e * Bc 2
 
2m *
2
and, from earlier  
2m * 2
Combining these two equations, and recognising the temperature dependence
of Bc2 and  explicitly, gives

Bc 2 ( T ) 
e * 2 ( T )
If Bc2=3 Tesla
then  = 10nm
However we have also just shown that the thermodynamic critical flux density,
1 
Bc, is given by
Bc (T )(T ) * (T ) 
So, we obtain
Bc 2 (T)   2 Bc (T)
2 e*
where   (T) (T) is the
Ginzburg-Landau parameter
If <1/2 then Bc2 < Bc and as the magnetic field is
decreased from a high value the superconducting state
appears only at and below Bc
TYPE I
Superconductivity
If >1/2 then Bc2 > Bc and as the magnetic field is
TYPE II
decreased from a high value the superconducting state
Superconductivity
appears at and below Bc2 and flux exclusion is not complete
Lecture 7
Superconductivity and Superfluidity
The Quantisation of Flux
We are used to the concept of magnetic flux density being able to take
any value at all. However we shall see that in a Type II superconductor
magnetic flux is quantised.
To show this, we shall continue with the concept of the superconducting
wavefunction introduced by Ginzburg and Landau
(r )  (r ) ei(r )  (r ) ei(p.r ) 
where p=m*v is the momentum of the
superelectrons
In one dimension (x) this wave function can be written in the standard
form
 x

p   sin2  vt 

 
where =h/p
Note that here  is the wavelength of the wavefunction not the penetration depth
Lecture 7
Superconductivity and Superfluidity
The Quantisation of Flux
 x

p   sin2  vt 

 
If no current flows, p=0, = and the phase of the wavefunction at X, at Y and
all other points is constant
X
Y
If current flows, p is small, =h/p and there is a phase difference between X
Y
and Y
x̂
XY  X  Y  2

X
Now the supercurrent density is Js  e * vn*s
and
XY
Y
.dl
he * n*s
so  
m * Js
2m *
 *
JS . dl
hnse * X

this is the phase difference arising just from the flow of current
Lecture 7
Superconductivity and Superfluidity
The Quantisation of Flux
An applied magnetic field can also affect the phase difference between X and
Y by affecting the momentum of the superelectrons
As before, the vector p  m * v  e * A must be conserved during the application
of a magnetic field
The additional phase difference between X and Y on applying a magnetic field
is therefore
Y
2e *
A .dl
h X

And the total phase difference is
XY
Phase difference
due to current
Lecture 7
Y
Y
2m *
2e *
 *
JS . dl 
A .dl
h
hnse * X
X


Phase difference due to
change of flux density
Superconductivity and Superfluidity
The Quantisation of Flux
We know that in the centre of a superconductor the
current density is zero
XY
So if we now join the ends of the path XY to form a
superconducting loop the line integral of the current
density around a path through the centre of XY
must be zero
XY
Y
Y
2m *
2e *
 *
JS . dl 
A .dl
h
hnse * X
X


Also we know (eg from the Bohr-Sommerfeld model of the atom) that the phase
at X and Y must now be the same…... …...so an integral number of
wavelengths must be sustained around the loop as the field changes
Hence
Lecture 7
XY
Y
2e *
 N2 
A .dl
h X

Superconductivity and Superfluidity
The Quantisation of Flux
The integral
Y
 A .dl
XY
X
is simply the flux threading the loop, ,
Y
so
and
2e *
2e *
A .dl 
  N2
h X
h

 N
h
 No
e*
So the flux threading a superconducting loop must be quantised in units of
o 
h
e*
where o is known as the flux quantum
We shall see later that e* 2e, in which case o =2.07x10-15 Weber
This is extremely small (10-6 of the earth’s magnetic field threading a 1cm2 loop)
but it is a measurable quantity
Lecture 7
Superconductivity and Superfluidity
Quantisation of flux
Although the flux quantum
o 
h
e*
is extremely small it is nevertheless measurable
Quantisation of flux can be shown by repeatedly measuring the magnetisation
of a superconducting loop repeatedly cooled to below Tc in a magnetic fields of
varying strength
…..analogous to Millikan’s oil drop experiment
magnetisation
For all known superconductors
it is found that e* 2e and
o =2.07x10-15 Weber
Superconductivity is therefore a
manifestation of macroscopic
quantum mechanics, and is the
basis of many quantum devices
such as SQUIDS
time
Lecture 7
Superconductivity and Superfluidity
A single vortex
We have seen that in a Type II superconductor small narrow
tubes of flux start to enter the bulk of the superconductor at
the lower critical field Hc1
We now know that these tubes must be quantised
The very first flux line that enters at Hc1 must therefore contain a single flux
quantum o Therefore
o
Hc1 
o 2
Also the energy per unit length associated with the creation of the flux line
is so E  o2
1  H2
2 o c1
However if a single flux line contained n flux quanta the associated energy would
be E  n2o2
It is clearly energetically more favourable to create n flux lines each of one flux
quanta, for which E  no2
the flux lines on the micrograph above therefore represent single flux quanta!
Lecture 7
Superconductivity and Superfluidity
The mixed state in Type II superconductors
Hc1< H <Hc2
B
The bulk is diamagnetic but it is threaded with normal
cores
The flux within each core is generated by a vortex of
supercurrent
Hc1
0
Hc2
H
-M
Lecture 7
Superconductivity and Superfluidity
The flux line lattice
flux line
curvature
Hexagonal
lattice
Defects and
disorder
Lower density
of flux lines
Lecture 7
Superconductivity and Superfluidity